Enhanced dye durability through controlled dye environment

ABSTRACT

An interpenetrating polymer network (IPN) or semi-interpenetrating polymer network (semi-IPN) comprises a first phase which is continuous and comprises a flexible polymer and a second phase which is a fluorescent or nonfluorescent durable dispersed or continuous phase and comprises a dye and a polymer, wherein the polymer enhances durability of the dye. Such networks are particularly useful in fluorescent traffic signs or safety devices or in pavement marking tape or paint.

CROSS REFERENCE TO RELATED APPLICATIONS

This application is a divisional of U.S. application Ser. No.09/387,996, filed Sep. 1, 1999, now pending.

The application is Divisional of Ser. No. 09/387,996, filed Sep. 1,1999, now U.S. Pat. No. 6,395,844 which is Divisional of Ser. No.08/957,291, filed Oct. 24, 1997, now U.S. Pat. No. 6,001,936.

FIELD OF THE INVENTION

This invention relates to interpenetrating polymer networks andsemi-interpenetrating polymer networks comprising a fluorescent dye ornon-fluorescent having enhanced durability.

BACKGROUND OF THE INVENTION

Articles containing colorants are known to lose their color when exposedto solar radiation for extended times. In particular, fluorescentcolorants degrade more quickly than conventional colorants, oftenturning colorless on exposure to daily solar radiation in a matter ofdays or months. Even though they are less durable, fluorescent dyes arecommonly used for increased visibility of an article due to the visualcontrast between a dyed article and its surroundings. Increasedvisibility is particularly important, for instance, in the traffic signindustry. Fluorescent colored signs have been shown to increase motoristand pedestrian safety, but their use remains limited due to their poorcolor stability and the need to frequently replace them in order tomaintain effective performance.

Attempts to maintain color of fluorescent articles have included addingultraviolet (UV) overlay screens which effectively filter radiationbelow 380 nm. Such protective overlays add cost and complexity tootherwise low-maintenance articles. Hindered amine light stabilizers(HALS) have been added to polycarbonate matrixes to enhance thedurability of fluorescent dyes contained therein.

Interpenetrating polymer networks (IPNs), systems comprising twoindependent crosslinked polymer networks, have been described. See, forexample, Encyclopedia of Polymer Science and Engineering Vol. 8; JohnWiley & Sons, New York (1987) p. 279 and L. H. Sperling, Introduction toPhysical Polymer Science, John Wiley & Sons (1986) pp. 46-47. Inparticular, IPNs comprising acrylate and urethane networks have beenprepared by either sequential or simultaneous (but independent)polymerization of free-radically polymerizable ethylenically-unsaturatedacrylate-type monomers and urethane precursors (i.e., polyisocyanate andpolyhydroxy coreactants). See, for example, U.S. Pat. Nos. 4,128,600,4,342,793, 4,921,759, 4,950,696, 4,985,340, 5,147,900, 5,256,170,5,326,621, 5,360,462, and 5,376,428.

Single phase polymers comprising pigments or dyes have been disclosed.See, for example, U.S. Pat. Nos. 3,253,146, 5,605,761, and 5,672,643.

SUMMARY OF THE INVENTION

Briefly, the present invention provides an interpenetrating polymernetwork (IPN) or semi-interpenetrating polymer network (semi-IPN)comprising

a) a first phase being a continuous phase and comprising a flexiblepolymer, and

b) a second phase being a ntiorescently durable dispersed or continuousphase and comprising a fluorescent dye and a polymer, wherein thepolymer enhances durability of the fluorescent dye.

Preferably the polymer of the first phase has a Tg of at most 40° C.,preferably at most 30° C. to impart flexibility of the IPN or semi-IPNunder use conditions.

In another aspect, the present invention provides a multilayerconstruction comprising a substrate having on at least one surfacethereof a substantially transparent fluorescent layer, the multilayerconstruction being a pavement marking tape.

In yet another aspect, this invention relates to an IPN or semi-IPN inwhich a conventional dye replaces the fluorescent dye described above.

In still a further aspect, this invention provides a method of enhancingthe color durability of a fluorescent or non-fluorescent dye in an IPNor semi-IPN comprising the step of:

providing an IPN or semi-IPN comprising:

a first phase being a continuous phase and comprising a flexiblepolymer, and

a second phase being a durable colored dispersed or continuous phasecomprising a dye therein, wherein the polymer enhances durability of thedye.

In the present invention, the mechanical properties of the IPN orsemi-IPN are controlled by the first phase polymer, and the localenvironment of the dye is controlled by the second phase. This providesthe advantage of optimizing the mechanical properties, such asflexibility, conformability, abrasion-resistance, and toughness, and thedye environment independently of one another.

A dye can be covalently bound to the polymer in the second phase, or itcan be soluble in the polymer of the second phase. Preferably, it iscovalently bound to the polymer of the second phase.

In this application:

“acrylate” means acrylic and methacrylic acid and esters thereof;

“conventional colorant” means colorants which do not exhibit fluorescentproperties to the unaided eye;

“dye” means a colors(It that can be dissolved in the matrix in which itresides;

“flexible” means capable of bending around a mandrel of 3 mm diameterwithout cracking at 23° C.;

“fluorescent dye” means a compound that exhibits fluorescent propertiesto the unaided eye;

“fluorescently durable” means enhanced retention of fluorescencerelative to a single phase system upon exposure to weathering;

“group” or “compound” or “ligand” or “monomer” or “polymer” means achemical species that allows for substitution or which may besubstituted by conventional substitutents which do not interfere withthe desired product; e.g., substitutents can be alkyl, alkoxy, aryl,phenyl, halo (F, Cl, Br, I), cyano, nitro, etc.;

“hindered amine light stabilizer” means sterically hindered amines ofthe class of compounds preferably represented by 2,2,6,6-tetraalkylpiperidines;

“interpenetrating polymer network” means a network of two or morepolymers (two phases) that is formed by independent polymerization oftwo or more monomers in the presence of each other so that the resultingindependent crosslinked polymer networks are physically intertwined butare essentially free of chemical bonds between them; there is producedan entangled combination of two crosslinked polymers that are not bondedto each other;

“organometallic compound” means a chemical substance in which at leastone carbon atom of an organic group is bonded to a metal atom (BasicInorganic Chemistry, F. A. Cotton, G. Wilkinson, Wiley, New York, 1976,p. 497); and “metal” means any transition metal from Periodic Groups4-10;

“semi-interpenetrating polymer network” means a polymer network of twoor more polymers that is formed by independent polymerization of two ormore monomers so that the polymers (two phases) are independent but arephysically intertwined and are essentially free of chemical bondsbetween them and wherein at least one polymer is crosslinked, i.e.,thermoset, and at least one is uncrosslinked, i.e., thermoplastic; thereis produced an entangled combination of two polymers, one of which iscrosslinked, that are not bonded to each other; and

“weathering” means exposing an article to either natural or artificialenvironments which include heat, moisture, and radiation.

There is a continuing need lor articles that exhibit enhancedfluorescence and color durability. In particular, fluorescent articlesthat retain their color and/or fluorescent properties out of doorswithout requiring, e.g., protective overlays, are needed.

A desire for flexible fluorescent products has led to work inpolyvinylchloride, olefin copolymers and polyurethanes. Unfortunately,when these resins are employed as hosts for fluorescent dyes, poor colorretention results. Factors contributing to the reduction in colorinclude lack of dye solubility in the host matrix, dye migration, andminimal protection offered by the resin against photodegradation.

Dispersal of a second phase, preferably an acrylate phase, morepreferably an aromatic acrylate phase, into these thermoplastic resinsreduces the above mentioned drawbacks. Preferably, it provides for thecovalent attachment of the fluorescent dye, thus preventing physicalloss of the dye and provides a protective environment for the dyeagainst photodegradation.

IPNs or semi-IPNs can include polymers that can comprise as a firstphase any of crosslinked and/or thermoplastic polyurethanes,polyolefins, copolymers of olefins preferably with acrylates, blockcopolymers, polyvinyl chloride, natural and synthetic rubbers, as wellas silicone rubber, and fluoroelastomers.

The second phase of the IPNs and semi-IPNs of the invention, which isthe phase that includes a dye, preferably a fluorescent dye, can be adispersed phase or a continuous phase. Polymers that can comprise thesecond phase include acrylates, epoxies, and cyanate esters, andpreferably comprises an acrylate polymer with aromatic content.

The advantage of this approach is that dye color retention can beimproved while maintaining desired physical properties. Depending on theproduct application, physical propertics may incluide flexibility,strength, transparency or thermoformability. This can be achievedthrough the use of a two-phase IPN or semi-IPN system where thefluorescent dye preferably is reacted into a crosslinked dispersedsecond phase in a continuous first phase. Therefore, the continuousfirst phase dominates the physical properties, and the dispersed secondphase serves to anchor the dye and improve photodurability. Theadvantage lies in the independent optimization of both phases. The firstphase can be chosen for a particular physical property while thedispersed second phase can be chosen for enhanced dye photodurability.For instance, accelerated weathering studies have shown thatphotodurability is improved when the dispersed second phase comprisesaromatic components.

Semi-IPNs and IPNs can be prepared by a modified extrusion processamenable to existing product manufacturing. They can be extruded ontoliners or onto other webs such as pavement marking tapes. Curing of thedispersed second phase can occur thermally or by radiation curing afterdesired processing.

Solventless processing is another advantage of the IPNs and semi-IPNs ofthe present invention. For example, with IPNs comprising urethanes andacrylates, the acrylate monomners act as reactive diluents such that nosolvents are needed to obtain a coatable viscosity. Additionally, IPNsand semi-IPNs offer several cure options. In the case of IPNs, monomerscanbe polymerized simultaneously or the monomers can be polymerizedsequentially in either order. An advantage of sequential polymerizationsis that after one of the phases is cured, the sample can undergoadditional processing before the second phase is cured. This sequence istypical of IPN processing. In addition, many polymerizations can beinitiated by different methods, such as thermal or radiation cure ofacrylates. Therefore, numerous processing options can be identified foreach IPN or semi-IPN system.

IPNs and semi-IPNs of the present invention find use as fibers, fabrics,canvas markings, roll-up signs, barrel wraps, cone sleeves, truckmarkings, license plates, safety vests, pavement marking paints andtapes, reflective films, and other articles where flexible materialshaving dye durability are desired. These materials preferably arefluorescent. The materials of the present invention are particulirlyi.seftul in safety applications and devices, such as in fluorescenttraffic signs, where dye stability and durability is highly valued.

IPNs and semi-IPNs of the present invention are superior to knownmaterials because there is produced a flexible article which not onlyprovides a mechanism for covalent dye attachment, but also retards dyedegradation. Preferred IPNs and semi-IPNs are transparent so as not tointerfere with optical properties of the article.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

IPNs and semi-IPNs of the present invention comprise a first phase whichis a continuous phase and to a great extent contributes mechanicalproperties, including flexibility, to the final network. Polymers thatcan comprise the first phase include crosslinked and/or thermoplasticpolyurethanes, polyolefins, copolymers of olefins preferably withacrylates, polyvinyl chloride, block copolymers, natural and syntheticrubbers, as well as silicone rubber, and fluoroelastomers. Preferably,the first phase is present in an amount by weight that is greater thanthat of the second phase, i.e., greater than 50 weight percent of theIPN or semi-IPN.

The second phase of the IPNs and semi-IPNs of the invention, which isthe phase that includes a dye, which preferably is a fluorescent dye,can be a dispersed phase or a continuous phase. Polymers that cancomprise the second phase include acrylates, epoxies, and cyanateesters, and preferably comprises an acrylate polymer with aromaticcontent. Preferably, the network of the second phase is present in anamount by weight that is less than that of the first phase, i.e., lessthan 50 percent by weight. Preferably, the polymer of the second phasehas aromatic content and is crosslinked.

Preferred IPNs of the invention include those wherein the first phase isa polyurethane that is formed by a condensation reaction between anisocyanate and an alcohol, and wherein the second phase is an acrylatenetwork formed by free radical chain polymerization of one or moreacrylate monomers. The resulting networks are held together by permanententanglements.

Preferred semi-IPNs of the invention include those wherein the firstphase is a commercially available thermoplastic polyolefin copolymer,and wherein the second phase is an acrylate network formed by freeradical chain polymerization of one or more acrylate monomers.

Morphology of the IPN or semi-IPN can be controlled, for example, byutilizing compatibilizing agents that promote chemical or physicalinteractions between the phases. Represenitative examples includehydroxy-functional acrylates, diol-functional acrylates,amine-functional acrylates, hydroxy-functional epoxies, and blockcopolymers, as is known in the art.

IPNs and semi-IPNs of the present invention are prepared by methodsknown in the art. See, for example, D. Klempner, Editor,“Interpenetrating Polymer Networks”, American Chemical Society,Washington, D.C. (1994).

The IPNs of the present invention can be prepared by simultaneous cureof a mixture of acrylate monomer(s) via free-radical polymerization andurethane precursors, namely polyisocyanates and polyfunctional alcohols,via condensation polymerization.

All components, used in the present invention, unless otherwise stated,are either commercially available or can be prepared by methods known inthe art.

A wide variety of acrylate monomers and/or oligomers can be used inpreparing the second phase of the IPN or semi-IPN of the invention,including mono-, di-, and polyacrylates and -methacrylates, such asmethyl acrylate, methyl methacrylate, ethyl acrylate, isopropylmethacrylate, isooctyl acrylate, n-hexyl acrylate, 2-ethylhexylacrylate, stearyl acrylate, isobornyl acrylate, tetrahydrofurfurylacrylate, perfluorinated octyl acrylate, caprolactone acrylate, allylacrylate, glycerol diacrylate, ethylene glycol diacrylate, diethyleneglycol diacrylate, triethylene glycol dimethacrylate, 1,3-propanedioldiacrylate, 1,3-propanediol dimethacrylate, 1,6-hexanediol diacrylate,1,8-hexanediol diacrylate, neopentyl glycol diacrylate,1,4-cyclohexanediol diacrylate, propoxylated neopentyl glycoldiacrylate, glycerol triacrylate, trimethylolpropane triacrylate,1,2,4-butanetriol trimethacrylate, pentaerythritol triacrylate,pentaerythritol tetraacrylate and -tetramethacrylate, sorbitolhexaacrylate, bis[1-(2-acryloxy)]-p-ethoxyphenyl dimethylmethane,bis[1-(3-acryloxy-2-hydroxy)]-p-propoxyphenyl dimethylmethane,tris-hydroxyethylisocyanurate trimethacrylate, bis-acrylates andbis-methacrylates of polyalkylene glycols, and combinations thereof.Acrylate monomers having aromatic content include benzyl acrylate,phenoxyethyl acrylate, phenoxyethyl methacrylate, tribromophenoxyethylacrylate, ethoxylated bisphenol A diacrylate, bisphenol Adimethacrylate, and (2-phenylthio)ethyl acrylate. Preferred acrylatesinclude the above named aromatic acrylates.

Preferably, a combination of a monofunctional acrylate or methacrylateand a polyfunctional, preferably difunctional, acrylate or methacrylate,is used in the IPNs or semi-IPNs of the invention. The monofunctionalacrylate or methacrylate monomer(s) may be selected from the groupconsisting of isooctyl acrylate, tetrahydroftirfuryl acrylate,phenoxyethyl acrylate, isobornyl acrylate, perfluorinated octylacrylate, caprolactone acrylate, and combinations thereof. Thepolyfunctional acrylate or methacrylate monomer(s) may be selected fromthe group consisting of propoxylated neopentyl glycol diacrylate,1,6-hexanediol diacrylate, 1,3-propanediol diacrylate,trimethylolpropane triacrylate, ethoxylated bisphenol A diacrylate, andcombinations thereof.

Thermal initiators useful in preparing acrylates included in the IPNs orsemi-IPNs comprise, but are not limited to, azo, peroxide, persulfateand redox initiators.

Suitable azo initiators include, but are not limited to,2,2′-azobis(4-methoxy-2,4-dimethylvaleronitrile) (VAZO™ 33),2,2′-azobis(2-amidinopropane)dihydrochloride (VAZO™ 50),2,2′-azobis(2,4-dimethylvaleronitrile) (VAZO™ 52),2,2′-azobis(isobutyronitrile) (VAZO™ 64),2,2′-azobis(2-methylbutyronitrile) (VAZO™ 67), and1,1′-azobis(1-cyclohexanecarbonitrile) (VAZO™ 88), all of which areavailable from DuPont Chemicals, Wilmington, Del., and2,2′-azobis(methyl isobutyrate) (V-601™), available from Wako ChemicalsUSA Inc., Richmond, Va.

Suitable peroxide initiators include, but are not limited to, benzoylperoxide, acetyl peroxide, lauryl peroxide, decanoyl peroxide, diacetylperoxydicarbonate, di(4-t-butylcyclohexyl)peroxydicarbonate (PERKADOX™16), available from Akzo, Nobel Chemicals, Inc., Chicago, Ill.,di(2-ethylhexyl)peroxydicarbonate, t-butylperoxypivalate (Lupersol™ 11),available from Elf Atochem North America, Philadelphia, Pa.,t-butylperoxy-2-ethylhexanoate (Trigonox™ 21-C50), available from Akzo,Nobel Chemicals, Inc., and dicumyl peroxide.

Suitable persulfate initiators include, but are not limited to,potassium persulfate, sodium persulfate, and ammonium persulfate.

Suitable redox (oxidation-reduction) initiators include, but are notlimited to, combinations of the above persulfate initiators withreducing agents such as sodium metabisulfite and sodium bisulfite;systems based upon organic peroxides and tertiary amiiics, such asbenzoyl peroxide plus dimethylaniline; and systems based on organichydroperoxides and transition metals, such as cumene hydroperoxide pluscobalt naphthenate.

Other initiators include, but are not limited to, pinacols, such asteteraphenyl-1,1,2,2-ethanediol.

Preferred thermal free radical initiators are selected from the groupconsisting of azo compounds and peroxides. Most preferred are benzoylperoxide, Lupersol™ 11, and Perkadox™ 16, and combinations thereof.

The initiator is present in a catalytically-effective amount and suchamounts are typically in the range of from about 0.01 to about 5 percentby weight, and preferably in the range of from about 0.025 to about 2percent by weight, based on the weight of the total IPN or semi-IPNformulation. If a mixture of initiators is used, the total amount of themixture of initiators would be as if a single initiator was used.

Photoinitiators that are useful for polymerizing acrylate monomersinclude the benzoin ethers, such as benzoin methyl ether or benzoinisopropyl ether; substituted benzoin ethers, such as anisoin methylether; substituted acetophenones, such as 2,2-diethoxyacetophenone and2,2-dimethoxy-2-phenylacetophenone; substituted alpha-ketols, such as2-methyl-2-hydroxypropiophenone; aromatic sulfonyl chlorides, such as2-naphthalene-sulfonyl chloride; bis-acyl phosphine oxides, such asbis-(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentylphosphine oxide and2,4,6-trimethylbenzoyl diphenyl phosphine oxide; photoactive oxiines,such as 1-phenyl-1,1-propanedione-2(o-ethoxycarbonyl)oxime; and mixturesthereof. They may be used in amounts, which as dissolved provide about0.01 to about 5 percent by weight of the acrylate monomer, preferably inthe range of about 0.25 to about 2 percent by weight of the total IPNformulations. If a mixture of initiators is used, the total amount ofthe mixture of initiators would be as if a single initiator was used.

Optionally, it is within the scope of this invention to includephotosensitizers or photoaccelerators in the radiation-sensitivecompositions. Use of photosensitizers or photoaccelerators alters thewavelength sensitivity of radiation-sensitive compositions employed asinitiators of this invention. This is particularly advantageous when theinitiator does not strongly absorb the incident radiation. Use oflaphotosensitizer or photoaccelerator increases the radiation sensitivityallowing shorter exposure times and/or use of less powerful sources ofradiation. Any photosensitizer or photoaccelerator may be useful if itstriplet energy is at least 45 kilocalories per mole. Examples of suchphotosensitizers are given in Table 2-1 of the reference, S. L. Murov,Handbook of Photochemistry, Marcel Dekker Inc., N.Y., 27-35 (1973), andinclude pyrene, fluoranthrene, xanthone, thioxanthone, benzophenone,acetophenone, benzil, benzoin and ethers of benzoin, chrysene,p-terphenyl, acenaphthene, naphthalene, phenanthrene, biplienyl,substituted derivatives of the preceding compounds, and the like. Whenpresent, the amount of photosensitizer or photoaccelerator used in thepractice of the present invention is generally in the range of 0.01 to10 parts, and preferably 0.1 to 1.0 parts, by weight of photosensitizeror photoaccelerator per part of initiator.

The polyisocyanate component of the polyurethane precursors useful inthe practice of the present invention may be any aliphatic,cycloaliphatic, aromatic or heterocyclic polyisocyanate, or anycombination of such polyisocyanates. Particularly suitablepolyisocyanates correspond to the formula

Q(NCO)_(p)  (I)

in which p is an integer of from 2 to 4; and

Q represents:

an aliphatic hydrocarbon di-, tri-, or tetra-radical containing from 2to 100 carbon atoms and zero to 50 heteroatoms;

a cycloaliphatic hydrocarbon radical containing from 4 to 100 carbonatoms and zero to 50 heteroatoms;

an aromatic hydrocarbon radical or heterocyclic aromatic radicalcontaining from 5 to 15 carbon atoms and zero to 10 heteroatoms; or

an araliphatic hydrocarbon radical containing from 8 to 100 carbon atomsand zero to 50 heteroatoms. The heteroatoms that can be present in Qinclude non-peroxidic oxygen, sulfur, non-amino nitrogen, halogen,silicon, and non-phosphino phosphorous.

Examples of polyisocyanates are as follows: ethylene diisocyanate,1,4-tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate,trimethyl hexamethylene diisocyanate, 1,12-dodecane diisocyanate,cyclobutane-1,3-diisocyanate, cyclohexane-1,3- and -1,4-diisocyanate,1-isocyanato-3,3,5-trimethyl-5-isocyanotomethylcyclohexane (isophoronediisocyanate, IDPI), 2,4- and 2,6-hexahydrotolylene diisocyanate,perhydro-2,4′- and -4,4′-diphenylmethane diisocyanate (H₁₂MDI),hexahydro-1,3- and -1,4-phenylene diisocyanate, 1,3- and -1,4-phenylenediisocyanate, 2,4- and 2,6-tolylene diisocyanate, diphenylmethane-2,4′-and -4,4′-diisocyanate, mixtures of 2,2,4- and 2,4,4-trimethylhexamethylene diisocyanate (TMDI), naphthylene-1,5-diisocyanate,including mixtures of these isomers, as well as oligomers thereof, andany combination of the above diisocyanates.

IPNs or semi-IPNs of the invention can also be prepared using, forexample, triphenylmethane-4,4′,4″-triisocyanate, polyphenylpolymethylene polyisocyanates (British Patent Nos. 874,430 and 848,671);m- and p-isocyanatophenyl sulfonyl isocyanates (U.S. Pat. No.3,454,606); perchlorinated aryl polyisocyanates (U.S. Pat. No.3,227,138); polyisocyanates containing carbodiimide groups (U.S. Pat.No. 3,152,162); norbomane diisocyanates (U.S. Pat. No. 3,492,330);polyisocyanates containing allophanate groups (such as DESMODUR XP7040™, available from Bayer Chemicals, Pittsburgh, Pa.); polyisocyanatescontaining isocyanurate groups (such as DESMODUR N-3300™, available fromBayer Chemicals); polyisocyanates containing urethane groups (U.S. Pat.No. 3,396,164 and 3,664,457); polyisocyanates containing acrylated ureagroups (German Patent No. 1,230,778); polyisocyanates containing biuretgroups (such as DESMODUR N-100™, available from Bayer Chemicals);polyisocyanates produced by telomerization reactions (U.S. Pat. No.3,654,106); polyisocyanates containing ester groups (U.S. Pat. No.3,567,763); polyisocyanates prepared from the reaction of any of theabove-mentioned diisocyanates with acetals (German Patent No. 1,072,385)and polyisocyanates containing polymeric fatty acid esters (U.S. Pat.No. 3,455,883).

Preferred polyisocyanates for use in films of the invention includeDesmodur N-100™, Desmodur XP 7040E™, Desmodur N-3300™and combinationsthereof.

Suitable co-reactants with polyisocyanates for formation of thepolyurethane component of the IPN or semi-IPN are compounds containingone or more reactive hydroxyl groups, particularly compounds containingfrom about 2 to about 50 hydroxyl groups and above all, compounds havinga weight average molecular weight of from about 50 to about 25000,preferably from about 700 to about 2000. For example, polyesters,polyethers, polythioethers, polyacetals, polycarbonates,poly(meth)acrylates, polyurethanes, and polyester amides containing atleast 2, generally 3 or more hydroxyl groups, as well ashydroxyl-containing prepolymers of these compounds reacted with aless-than-equivalent quantity of polyisocyanates (of the type known forproduction of polyurethanes) can be used in the present invention.

Co-reactants with polyisocyanates can also include compounds containingone or more reactive amine groups, such as, for example, XP-7053™,XP-7059™ and XP-7068™ aspartic esters (available from Bayer Corp.,Pittsburgh, Pa.).

Low molecular weight compounds containing at least twoisocyanate-reactive hydrogen atoms (molecular weight of from about 50 toabout 400) suitable for use in accordance with the present invention arecompounds preferably containing hydroxyl groups and generally containingfrom 2 to about 8, and preferably from 2 to about 4 isocyanate reactivehydrogen atoms. Combinations of different compounds containing at leasttwo isocyanate-reactive hydrogen atoms and having a molecular weight inthe range of from about 50 to about 400 can also be used. Examples ofsuch compounds include ethylene glycol, 1,2- and 1,3-propane diol, 1,2-,1,3-, 1,4- and 2,3-butane diol, 1,5-pentane diol, 1,6-hexane diol,1,8-octane diol, neopentyl glycol, 1,4-bishydroxymethyl cyclohexane(1,4-cyclohexane dimethanol), 2-methyl-1,3-propane diol, dibromobutenediol, glycerol, trimethylolpropane, 1,2,6-hexanetriol,2,2-dimethyl-1,3-propane diol, 1,6- and 2,5-hexane diol, 1,12-dodecanediol, 1,12- and 1,18-octadecane diol, 2,2,4- and2,4,4-trimethyl-1,6-hexane diol, trimethylol propane,cyclohexane-1,4-diol, 2,2-bis-(4-hydroxycyclohexyl)-propane,1,4-bis-(ω-hydroxyethoxy)-benzene, 1,3-bis-hydroxyalkyl hydantoins,tris-hydroxyalkyl isocyanurates andtris-hydroxyalkyl-triazolidane-3,5-diones, trimethylolethane,pentaerythritol, quinitol, mannitol, sorbitol, diethylene glycol,triethylene glycol, tetraethylene glycol, dipropylene glycol, higherpolypropylene glycols, higher polyethylene glycols, higher polybutyleneglycols, and combinations thereof.

Higher molecular weight polyols include the polyethylene andpolypropylene oxide polymers in the molecular weight range of from about200 to about 20,000, such as the Carbowax™ 400, 600, 800, 1000, 3350,8000 and 20000 series of poly(ethylene oxide) compounds (available fromUnion Carbide Corp., Danbury, Conn.), caprolactone polyols in themolecular weight range of from about 200 to about 5000, such as theTone™ 200, 210, 230, 240, 260, 301, 305, and 310 series of polyols(available from Union Carbide), poly(tetramethylene ether)glycols in themolecular weight range of from about 200 to about 4000, such as theTerathane™ 1000 and 2000 series of polyols (available from DuPont Co.,Wilmington, Del.), hydroxy-terminated polybutadiene materials, such asthe Poly bd™ series of polyols (available from Elf Atochem,Philadelphia, Pa.), polycarbonate diols, such as KM-10-1667™ andKM-10-1733™ (available from Stahl USA, Peabody, Mass.), polyurethanediols, such as K-flex UD-320-100™ (available from King Industries,Norwalk, Conn.), aromatic polyether polyols, such as Synfac 8024™™(available from Milliken Chemical, Spartanburg, S.C.), and randomcopolymers of poly(tetramethylenc oxidle)/polycarbonate, such as thePolyTHF™ CD series of polyols (available from 13ASI Corporation, MountOlive, N.J.). Preferred polyester polyols include the Desmophen™ family(available from Bayer, Pittsburgh, Pa., as Desmophen™ 670-80, 670-100,800, and 1100). A preferred acrylic polyol is Joncryl™ 587 (commerciallyavailable from S. C. Johnson & Son, Inc., Racine, Wis.).

Another group of preferred polyols consists of hydroxyalkylatedbisphenol derivatives. Preferred polyols in this group have thefollowing general formula:

{H—O—R¹—O—A—}₂—CR²R³

wherein R¹ is either a straight or branched or cyclic alkylene (e.g.,methylene, ethylene, butylene, decylene) group consisting of 1 to 10carbon atoms, or an aralkylene group consisting of 7 to 14 carbon atoms(e.g., benzylidene, 1,2-diphenylethylene, phenethylene); R² and R³independently may be an alkyl group, aralkyl group, cycloalkyl group,alkaryl group, or an aryl group of from 1 to about 30 carbon atoms(preferably methyl, ethyl, and trifluoromethyl) and none or from 1 toabout 10 heteroatoms, and R² and R³ together can comprise an alkylene,cycloalkylene, arylene, alkarylene or aralkylene group containing from 2to about 660 carbon atoms and none or from 1 to about 10 heteroatomssuch as O and N;

A can be a substituted or unsubstituted arylene group, preferably havingfrom 6 to about 12 carbon atoms, most preferably p-phenylene,o-phenylene or dimethylnaphthalene.

Specific preferred hydroxyalkylated bisphenols include9,9-bis-4-(2-hydroxyethoxyphenyl)fluorene (i.e., hydroxyethylatedbisphenol of fluorenone), 2,2-bis-4-(2-hydroxyethoxyphenyl)butane (i.e.,hydroxyethylated bisphenol of 2-butanone),2,2-bis-4-(2-hydroxyethoxyphenyl)hexafluoropropane (i.e.,hydroxyethylated bisphenol F), 2,2-bis-4-(2-hydroxyethoxyphenyl)propane,2,2-bis-4-(2-hydroxyethoxyphenyl)norbornane,2,2-bis-4-(2-hydroxyethoxyphenyl)-5,6-cyclopentanonorbornane, and1,1-bis-4-(2-hydroxyethoxyphenyl)cyclohexane.

Other polyols suitable for use in the production of the polyurethanesand epoxy resins useful in the invention are the hydroxyalkyl ethersobtained by the addition of optionally substituted alkylene oxides, suchas ethylene oxide, propylene oxide, butylene oxide and styrene oxide,onto the above-mentioned polyols.

Preferred examples of such polyols are diethylene glycol, triethyleneglycol, dipropylene glycol, tripropylene glycol, dibutylene glycol,1,4-bis-(2-hydroxyethoxy)cyclohexane,1,4-bis-(2-hydroxyethoxy-methyl)-cyclohexane,1,4-bis-(2-hydroxyethoxy)-benzene,4,4′-bis-(2-hydroxyethoxy)-diphenylmethane, -diphenylpropane, -diphenylether, -diphenyl sulphone, -diphenyl ketone and -diphenyl cyclohexane.

It is, of course, possible to use combinations of the above-mentionedcompounds containing at least two isocyanate-reactive hydrogen atoms andhaving a molecular weight of from about 50 to about 50000, e.g.,combinations of polyethers and polyesters.

Many other compounds containing isocyanate-reactive hydrogen atoms(e.g., amines) and polyisocyanates are useful in the present invention,as would be obvious to one skilled in the art.

Preferably, the hydroxyl-functional material is at least a diol and ispresent in an amount sufficient to provide an isocyanate-to-polyol ratioin the composition preferably between about 1.1:1 and 0.9:1.

Catalysts for polyurethane formation are known, typically includingcertain tertiary amines, salts of weak acids, and certain organometalliccompounds. While any of the known thermally-activatable catalysts can beused in preparing the polyurethane component of the inventive IPN orsemi-IPN, the metal salts of weak organic acids are preferred. Amongthese may be named dibutyltin dilaurate and tin octoate. Most preferredis dibutyltin dilaurate, for reasons of high catalytic activity,availability, and low cost.

Thermoplastic homopolymeric polyolefins useful in the first phase of theIPN or semi-IPN of the present invention include polyethylene,polypropylene, poly-1-butene, poly-1-pentenle, poly-1-hexeine,poly-1-octene and related polyolefins. Useful homopolymeric polyolefinsinclude polyethylene (e.g., Dow LDPE 4012™, available from Dow ChemicalCo., Midland, Mich.). Also useful are copolymers of alpha-olefins,including poly(ethylene-co-propylene) (e.g., SRD7462™, SRD7-463™ andDS7C50™, each of which is available from Shell Chemicals, Inc., Houston,Tex.), poly(propylenle-co-1-butene) (e.g., SRD6-328™, also availablefrom Shell Chemicals), and related copolymers. Useful copolymers arepoly(ethylene-co-propylene). Also useful is the Vestoplast™ series ofpolyolefins, available from Hüls America Inc., Piscataway, N.J.

Thermoplastic copolymers of olefins and acrylates that are useful in thefirst phase of the IPN or semi-IPN of the present invention includeethylene-methacrylic acid copolymer (Nucrel™ 699 and Surlyn™1706, E.I.DuPont, Wilmington, Del.), ethylene acrylic acid copolymer (Primacor™3440, Dow Chemical Company, Midland, Mich.), and ethylene copolymer ofmethacrylic acid and isobutyl acrylate (E.I. DuPont, Wilmington, Del.).

Thermoplastic polyurethanes are useful in the first phase of theinvention and can include both aliphatic and aromatic polyurethanes withpolyester, polycarbonate, polycaprolactone or polyether based polyols.Examples of polyester based aromatic polyurethanes include Morthane™CA9068-201, PS455-100, PS49-202, PS79-200, and CA101-200; examples ofpolycaprolactone based aromatic polyurethanes include Morthane™CP91-400, PC86-400 and PC75-400; and examples of polyether basedaromatic polyurethanes include Morthane™ PE90-200, PE88-204, PE889A-0205and CA888. Examples of polyester based aliphatic polyurethanes includeMorthane™ PN3429-219, PN03-214, L424-167, and PN343-200 and examples ofpolyether based aliphatic polyurethanles include Morthane™ PE193-100,PE192-100, PE299-100 and PE399-100. All of the above mentionedpolyurethanes are available from Morton International, Inc. (Chicago,Ill.).

Block copolymers arc another class of polymers useful in the first phaseof the invention. Block copolymers are characterized by alternatingblocks of different monomer compositions along the polymeric backbone.The alternating blocks could be arranged in a simple diblock fashion,where 2 polymers of different chemistries are linked together at oneterminus, or in a triblock fashion where 3 polymers of differentcheinistries could he linked together in a sequential fashion or 2polymers of the same chemical composition are linked to the 2 terminalends of a polynmer with a ditferent chemical composition. In thisfashion, block copolymers of infinite block chemistries and sequencescan be envisioned. Repeating sequences of blocks along a polymer chaincan also be envisioned. Allport and Janes review numerous blockcopolymer chemistries which may be useful in the present invention(Block Copolymers, D. C. Allport, W. H. Janes, Wiley, New York, 1973).Examples of block copolymer chemistries useful in the invention includevinyl block copolymers as exemplified by styrene-isoprene-styrenetriblock copolymers or styrene-butadiene-styrene triblock copolymers(Kraton D™ series of polymers, Shell Chemical Co., Naperville, Ill.),styrene-ethylene/butylene-styrene or styrene-ethylene/propylene-styrenetriblock copolymers (Kraton G™ series, Shell Chemical Co., Naperville,Ill.), poly(ether-ester) copolymers (Hytrel™ series, DuPont, Wilmington,Del.), poly(ester-amide) copolymers (Elvamide™ series, DuPont Co.,Wilmington, Del. or Ultramide™ series, BASF, West Germany), andpoly(ether-amide) copolymers (PEBAX™ series, Atochem, Paris, France).

Thermoplastic plasticized polyvinyl chloride is useful in the firstphase of the invention. Flexible polyvinyl chloride useful in theinvention include materials available from Alpha Gary (Alpha Chemicaland Plastics Corporation, Pineville, N.C.) including grades such as495-85, 2105FR-76, 2222N-78, 30006/E1-74, 3012/1-60, 2214-75, andS00354. Other commercially available flexible polyvinyl chloridesuitable for use in the invention can be obtained from Teknor Apex(Teknor Apex Co., Plastics Div., Pawtucket, R.I.) including gradesUltra™ 90-U656C-80 and 3500-70NT™, and from Geon Co. (Avon Lake, Ohio)including grades A-7000, A-5500, A-8500, A5D00, and A-8000 which areknown under the tradename Geon™.

Thermosettable epoxy resins useful in the practice of the presentinvention preferably comprise compounds which contain one or more 1,2-,1,3- and 1,4-cyclic ethers, which also may be known as 1,2-, 1,3- and1,4-epoxides. The 1,2-cyclic ethers ire preferred. Such compounds can besaturated or unsaturated, aliphatic, alicyclic, aromatic orheterocyclic, or can comprise combinations thereof. Compounds thatcontain more than one epoxy group (i.e., polyepoxides) are preferred.

Aromatic polycpoxides (i.e., compounds containing at least one aromaticring structure, e.g., a benzene ring, and more than one epoxy group)that can be used in the present invention include the polyglycidylethers of polyhydric phenols, such as Bisphenol A-type resins and theirderivatives, epoxy cresol-novolac resins, Bisphenol-F resins and theirderivatives, and epoxy phenol-novolac resins; and glycidyl esters ofaromatic carboxylic acids, e.g., phthalic acid diglycidyl ester,isophthalic acid diglycidyl ester, trimellitic anhydride trigylcidylester, and pyromellitic acid tetraglycidyl ester, and mixtures thereof.Preferred aromatic polyepoxides are the polyglycidyl ethers ofpolyhydric phenols, such as the EPON™ series of diglycidyl ethers ofBisphenol-A, including EPON 828 and EPON 1001F, available commerciallyfrom Shell Chemicals, Inc., Houston, Tex.

Representative aliphatic cyclic polyepoxides (i.e., cyclic compoundscontaining one or more saturated carbocyclic rings and more than oneepoxy group, also known as alicyclic compounds) useful in the presentinvention include the “ERL™” series of alicyclic epoxides commerciallyavailable from Union Carbide Corp., Danbury, Conn., such as vinylcyclohexene dioxide (ERL-4206),3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate (ERL-4221),3,4-epoxy-6-methylcyclohexylmethyl-3,4-epoxy-6-methylcyclohexanecarboxylate (ERL-4201), bis(3,4-epoxy-6-methylcycylohexylmethyl)adipate(ERL-4289), dipentene dioxide (ERL-4269), as well as2-(3,4-epoxycyclohexyl-5,1″-spiro-3″,4″-epoxycyclohexane-1,3-dioxane,4-(1,2-epoxyethyl)-1,2-epoxycyclohexane and2,2-bis(3,4-epoxycyclohexyl)propane. Preferred alicyclic polyepoxidesare the ERL™ series. Other commercially available cycloaliphatic epoxiesthat are useful in the present invention include vinyl cyclohexenemonoxide (Union Carbide Corp.), cyclohexene oxide (Aldrich Chemical Co.,Milwaukee, Wis.), vinyl cyclohexene dioxide (ERL 4206™, Union CarbideCorp.), and limonene oxide, linionene dioxide, and α-pinene oxide (thesethree being available from Elf Atochem, Philadelphia, Pa.).

Representative aliphatic polyepoxides (i.e., compounds containing nocarbocyclic rings and more than one epoxy group) include1,4-bis(2,3-epoxypropoxy)butane, polyglycidyl ethers of aliphaticpolyols such as glycerol, polypropylene glycol, 1,4-butanediol, and thelike, and the diglycidyl ester of linoleic dimer acid.

A wide variety of commercial epoxy resins are available and are listedor described in, e.g., the Handbook of Epoxy Resins, by Lee and Neville,McGraw-Hill Book Co., New York (1967), Epoxy Resins, Chemistry andTechnology, Second Edition, C. May, ed., Marcell Decker, Inc., New York(1988), and Epoxy Resin Technology, P. F. Bruinis, ed., lntersciencePublishers, New York, (1968). Any of the epoxy resins described thereinmay be useful in preparation of the IPNs and semi-IPNs of the invention.

Polyhydroxy compounds (e.g., “polyols”), as described above, can beuseful in the preparation of epoxy resins used in the invention.

It is within the scope of the present invention to include, as abireactive comonomer, compounds having, for example, both epoxyfunctionality and at least one other chemical functionality, such as,e.g., hydroxyl, acrylate, ethylenic unsaturation, carboxylic acid,carboxylic acid ester, and the like. An example of such a monomer isEbecryl™ 3605, commercially available from UCB Radcure, Inc., Atlanta,Ga., a bisphenol-A-type monomer having both epoxy and acrylatefunctionality.

Epoxy curatives of the present invention can be photocatalysts orthermal curing agents.

Catalysts of the present invention (also known as “initiators,” theterms being used interchangeably in the present invention) preferablycan be activated by photochemical means. Known photocatalysts are of twogeneral types: onium salts and cationic organometallic salts, and bothare useful in the invention.

Onium salt photoinitiators for cationic polymerizations include iodoniumand sulfonium complex salts. Uselul aromatic iodonium complex salts areof the general formula:

wherein

Ar¹ and Ar² can be the same or different and are aromatic groups havingfrom 4 to about 20 carbon atoms, and are selected from the groupconsisting of phenyl, thienyl, furanyl, and pyrazolyl groups;

Z is selected from the group consisting of oxygen, sulfur, acarbon-carbon bond,

 wherein R can be aryl (having from 6 to about 20 carbon atoms, such asphenyl) or acyl (having from 2 to about 20 carbon atoms, such as acetyl,or benzoyl), and

 wherein R₁ and R₂ are selected from the group consisting of hydrogen,alkyl radicals having from 1 to about 4 carbon atoms, and alkenylradicals having from 2 to about 4 carbon atoms;

m is zero or 1; and

X has the formula DQ_(n), wherein D is a metal from Groups IB to VIII ora metalloid from Groups IIIA to VA of the Periodic Chart of the Elements(Chemical Abstracts version), Q is a halogen atom, and n is an integerhaving a value of from 1 to 6. Preferably, the metals are copper, zinc,titanium, vanadium, chromium, magnesium, manganese, iron, cobalt, ornickel and the metalloids preferably are boron, aluminum, antimony, tin,arsenic or phosphorous. Preferably, the halogen, Q, is chlorine orfluorine. Illustrative of suitable anions are BF₄ ⁻, PF₆ ⁻, SbF₆ ⁻,FeCl₄ ⁻, SnCl₅ ⁻, AsF₆ ⁻, SbF₅OH⁻, SbCl₆ ⁻, SbF₅ ⁻², AlF₅ ⁻², GaCl₄ ⁻,InF₄ ⁻, TiF₆ ⁻², ZrF₆ ⁻, CF₃SO₃ ⁻ and the like. Preferably, the anionsare BF₄ ⁻, PF₆ ⁻, SbF₆ ⁻, AsF₆ ⁻, SbF₅OH⁻, and SbCl₆ ⁻. More preferably,the anions are SbF₆ ⁻, AsF₆ ⁻, and SbF₅OH⁻.

The Ar₁ and Ar₂ aromatic groups may optionally comprise one or morefused benzo rings (eg., naphthyl, benzothienyl, dibenzothienyl,benzofuranyl, dibenzofuranyl, etc.). The aromatic groups may also besubstituted, if desired, by one or more non-basic groups if they areessentially non-reactive with epoxide and hydroxyl functionalities.

Useful aromatic iodonium complex salts are described more fully in U.S.Pat. No. 4,256,828, which is incorporated herein by reference. Thepreferred aromatic iodonium complex salts are (Ar)₂IPF₆ and (Ar)₂I SbF₆.

The aromatic iodonium complex salts useful in the invention arephotosensitive only in the ultraviolet region of the spectrum. However,they can be sensitized to the near ultraviolet and the visible range ofthe spectrum by sensitizers for known photolyzable organic halogencompounds. Illustrative sensitizers include aromatic amines and coloredaromatic polycyclic hydrocarbons, as described in U.S. Pat. No.4,250,053, incorporated herein by reference.

Aromatic sulfonium complex salt initiators suitable for use in theinvention are of the general formula

wherein

R₃, R₄ and R₅ can be the same or different, provided that at least oneof the groups is aromatic. These groups can be selected from the groupconsisting of aromatic moieties having from 4 to about 20 carbon atoms(e.g., substituted and unsubstituted phenyl, thienyl, and furanyl) andalkyl radicals having from 1 to about 20 carbon atoms. The term “alkyl”includes substituted alkyl radicals (e.g., substituents such as halogen,hydroxy, alkoxy, and aryl). Preferably, R₃, R₄ and R₅ are each aromatic,and

Z, m and X are all as defined above with regard to the iodonium complexsalts.

If R₃, R₄ or R₅ is an aromatic group, it may optionally have one or morefused benzo rings (e.g., niriplithyl, benzotllienyl, dibenzothienyl,benzofuranyl, dibenzofuranyl, etc.). The aromatic groups may also besubstituted, if desired, by one or more non-basic groups if they areessentially non-reactive with epoxide and hydroxyl functiotnalities.

Triaryl-substituted salts such as triphenylsulfoniumhexafluoroantimonate and p-(phenyl(thiophenyl)diphenylsulfoniumhexafluoroantimonate are the preferred sulfonium salts. Useful sulfoniumsalts are described more fully in U.S. Pat. No. 4,256,828.

Aromatic sulfoniumn complex salts useful in the invention arephotosensitive only in the ultraviolet region of the spectrum. However,they can be sensitized to the near ultraviolet and the visible range ofthe spectrum by a select group of sensitizers such as described in U.S.Pat. Nos. 4,256,828 and 4,250,053.

Suitable photoactivatable organometallic complex salts useful in theinvention include those described in U.S. Pat. Nos. 5,059,701,5,191,101, and 5,252,694, each of which is incorporated herein byreference. Such salts of organometallic cations have the generalformula:

{(L¹)(L²)M^(m)}^(+e)X⁻

wherein

M^(m) represents a metal atom selected from elements of periodic groupsIVB, VB, VIB, VIIB and VIII, preferably Cr, Mo, W, Mn, Re, Fe, and Co;

L¹ represents none, one, or two ligands contributing π-electrons thatcan be the same or different ligands selected from the group consistingof substituted and unsubstituted acyclic and cyclic unsaturatedcompounds and groups, and substituted and unsubstittuted carbocyclicaromatic and heterocyclic aromatic compounds, each capable ofcontributing two to twelve π-electrons to the valence shell of the metalatom M. Preferably, L¹ is selected from the group consisting ofsubstituted and unsubstituted η³-allyl, η⁵-cyclopentadienyl,η⁷-cycloheptatrienyl compounds, and η⁶-aromatic compounds selected fromthe group consisting of η⁶-benzene and substituted η⁶-benzene compounds(e.g., xylenes) and compounds having 2 to 4 fused rings, each capable ofcontributing 3 to 8 π-electrons to the vilence shell of M^(m);

L² represents none or 1 to 3 ligands contribuitng an even number ofσ-electrons that can be the same or different ligands selected from thegroup consisting of carbon monoxide, nitrosonium, triphenyl phosphine,triphenyl stibine and derivatives of phosphorous, arsenic and antimony,with the proviso that the total electronic charge contributed to M^(m)by L¹ and L² results in a net residual positive charge of e to thecomplex; and

e is an integer having a value of 1 or 2, the residual charge of thecomplex cation;

X is a halogen-containing complex anion, as described above.

Examples of suitable salts of organometallic complex cations aredisclosed in the aforementioned patents.

Optionally, the organomnetallic salt initiators can be accompanied by anaccelerator such as an oxalate ester of a tertiary alcohol. Theaccelerator preferably comprises from about 0.1 to about 4% by weight ofthe total polymerizable mixture (thermoplastic component, thermosettingcomponent and catalyst(s)), more preferably about 60% of the weight ofthe metallocene initiator, as described in U.S. Pat. No. 5,252,694,incorporated herein by reference.

Useful commercially available initiators include FX-512™, an aromaticsulfonium complex salt (3M, St. Paul, Minn.), UVI™-6974, an aromaticsulfonium complex salt (Union Carbide Corp., Danbury, Conn.) andIRGACURE™ 261, a cationic organometallic complex salt (Ciba GeigyChemicals, Hawthorne, N.Y.).

Photoinitiators useful in the invention can be present in an amount inthe range of 0.01 to 10 weight percent, preferably 0.01 to 5, mostpreferably 0.1 to 2 weight percent based on total resin composition.

Certain thermally-activated curing agents for epoxy resins (e.g.,compounds that effect curing and crosslinking of the epoxide by enteringinto a chemical reaction therewith) are useful in the present invention.Preferably, such curing agents are thermally stable at temperatures atwhich mixing of the components takes place.

Suitable thermal curilg agents include aliphatic and aromatic primaryand secondary amines, e.g. bis-(4-aminophenyl)sulfone,bis-(4-aminophenyl)ether, and 2,2-bis-(4-aminophenyl)propane; aliphaticand aromatic tertiary amines, e.g., dimethylatninopropylaminie andpyridine; fluorene diamines, such as those described in U.S. Pat. No.4,684,678, incorporated herein by reference; boron trifluoride complexessuch as BF₃.Et₂O and BF₃.H₂NC₂H₄OH; imidazoles, such as methylimidazole;hydrazines, such as adipohydrazine; and guanidines, such astetramethylguanidine and dicyandiamide (cyanoguanidine, also commonlyknown as DiCy).

High temperature epoxy catalysts are particularly useful in the presentinvention. It has been found that simple pyridinium, quinolinium,indoleninium, benzothiazolium, alkyl, aryl and alkylaryl ammonium andphosphonium salts are effective initiators of the cationicpolymerization of epoxies in the 250 to 350° C. range. Because of thesehigh exotherm temperatures, these catalysts are particularly suited touse with extrusion temperatures of 200° C. or greater. The compositionsare stable in the extruder, i.e., they do not cure, eliminating problemsthat would be caused by crosslinking during this processing step.

Classes of salts useful as thermal curatives include pyridinium,quinolinium, benzoxazolium, benzothiazolium, indolenium, ammonium, andphosphonium salts. Structures of salts that have been found to beparticularly suitable as catalysts in the present invention include:

wherein R is an alkyl group or an aryl group, R′ is an alkyl group or anacyl group or an aryl group, R″ is an alkyl group or an aryl group, R′″is an alkyl group or an aryl group. R and R′ together can form a ringstructure of from 4 to 8 carbon atoms. (R, R′ and R′″ together can forma bicyclic ring structure.) Alkyl groups can have 1 to 12 carbon atoms,and aryl groups can be 1 to 3 fused rings (e.g., naphthalene) or joinedrings (e.g., biphenyl) having up to 30 carbon atoms. Each cationiccharge must be balanced by the appropriate number of anions, X⁻.

and wherein X⁻ can be as previously defined, preferably X⁻ is BF₄ ⁻, PF₆⁻, AsF₆ ⁻, SbF₆ ⁻, or CF₃SO₃ ⁻, and most preferably, X⁻ is PF₆ ⁻.wherein each R, R′, R″, R′″ independently can be an alkyl, aryl, oralkaryl group having up to 20 carbon atoms, and X is as previouslydefined.

Thermal curatives can be present in an amount such that the ratio ofepoxy equivalents to thermal curative equivalents is in the range of0.9:1 to 2:1.

Cyanate ester monomers useful in the practice of the present inventioncomprise at least two -OCN groups, and are given by the general formula

Q(OCN)_(p)  (II)

where p is an integer from 2 to 7, and wherein Q comprises a mono-, di-,tri-, or tetravalent aromatic hydrocarbon containing from 5 to 30 carbonatoms and zero to 5 aliphatic, cyclic aliphcltic, or polycyclicaliphatic, mono-, di-, or trivalent hydrocarbon linking groupscontaining 7 to 20 carbon atoms. Optionally, Q may comprise 1 to 10lieteroatoms selected from the group consisting of non-peroxidic oxygen,sulfur, noni-phosphino phosphorus, non-amino nitrogen, halogen, andsilicon. In general, any mono-, di-, or polyfunctional phenolic compoundreacted with cyanogen halide in the presence of a base to form a mono-,di-, or polyfunctional aromatic cyanate ester compound may be useful inthe present invention.

In the practice of the present invention monomers of formula II may bepartially cyclotrimerized to produce useful oligomers. Also, cyanateester monomers, and oligotilers thereof, may be used in combination withother cyanate ester monomers and/or oligomers. Optionally, usefulcombinations may also comprise one or more monoofunctionial cyanateester monomers (i.e., p in formula II is one).

Examples of useful cyanate ester monomers and oligomers include, but arenot limited to: 1,3- and 1,4-dicyanatobenzene;2-tert-butyl-1,4-dicyanatobenzene; 2,4-dimethyl-1,3-dicyanatobenzene;2,5-di-tert-butyl-1,4-dicyanatobenzene;tetramethyl-1,4-dicyanatobenzene; 4-chloro-1,3-dicyanatobezene;1,3,5-tricyanatobenzene; 2,2′- or 4,4′-dicyanatobiphenyl;3,3′,5,5′-tetramethyl-4,4′-dicyanatobiphenyl; 1,3-, 1,4-, 1,5-, 1,6-,1,8-, 2,6-, or 2,7-dicyanatonaphthalene; 1,3,6-tricyanatonaphthalene;bis(4-cyanatophenyl)methane; 2,2-bis(4-cyanatophenyl)propane (AroCy™B-10 commercially available from Ciba-Geigy Corp., Ardsley, N.Y., andSkylex™ resins available from Mitsubishi Gas Chemical Co., Tokyo);partially cyclotrimerized oligomers, such as AroCy™ B-30 or B-50 whereapproximately 30 and 50% of the cyanate ester groups of AroCy™ B-10 havebeen cyclotrimerized; 1,1,1-tris(4-cyanatophenyl)ethane;1,1-bis-(4-cyanatophenyl)ethane (AroCy™ L-10);bis(3,5-dimethyl-4-cyanatophenyl)methane (AroCy™ M-10); partiallycyclotrimerized oligomers of M-10, such as AroCy™ M-20, M-30, and M-50;2,2-bis(3,5-dichloro-4-cyanatophenyl)propane;2,2-bis(3,5-dibromo-4-cyanatophenyl)propane; bis(4-cyanatophenyl)ether;4,4′-(1,3-phenylenediisopropylidene)diphenylcyanate (AroCy™ XU-366);partially cyclotrimerized oligomers of XU-366, such as AroCy™ XU-378;bis(4-cyanato-phenyl)ketone; bis(4-cyanatophenyl)thioether;bis(4-cyanatophenyl)sulfone; tris(4-cyanato-phenyl)phosphite;tris(4-cyanatophenyl)phosphate; cyanated novolac oligomers having thegeneral formula:

wherein n is 4 or less, preferably 2 or less, including Primaset™ PT-30,PT-60, PT-90, (all commercially available from Allied-Signal Inc.), andAroCy™ XU-371 (commercially available from Ciba-Geigy Corp.); andpolyaromatic cyanate ester oligomers comprising polycyclic aliphaticdiradicals, having the general formula:

wherein n is 4 or less, preferably 2 or less, including Quatrex™ 7187,(available from Dow Chemical).

Preferred cyanate ester monomers and oligomers are those that exist as aliquid, or that exhibit a low melting temperature, e.g., below about 90°C. Liquid or low melting cyanates ester monomers and oligomers may beused individually or in combination with other cyanates ester monomersor oligomers provided that the resulting combination is also a liquid orlow melting composition.

Examples of preferred cyanate ester monomers and oligomers include, butare not limited to: 1,1-bis-(4-cyanatophenyl)ethane (AroCy™ L-10),2,2-bis(4-cyanatophenyl)propane (AroCy™ B-10),bis(3,5-dimethyl-4-cyanatophenyl)methane (AroCy™ M-10),4,4′-(1,3-phenylenediisopropylidene)diphenylcyanate (AroCy™ XU-366),cyanated novolac oligomers, e.g., those of formula III, and polyaromaticcyanate ester oligomers comprising polycyclic aliphatic diradicals,e.g., those of formula IV.

Polyhydroxyl compounds (e.g., “polyols”), as described above, can beuseful in the preparation of cyanate esters useful in the invention.

Cyanate esters useful in the present invention can be cured orpolymerized in the presence of an orgaiiometallic compound; that is, acompound containing at least one transition metal to carbon covalentbond, with the general formula

[L³L⁴L⁵M′]^(+e′)X′_(f)

wherein:

L³ represents none or 1 to 12 ligands contributing pi-electrons that canbe the same or different, and are selected from cyclic or acyclicaromatic, heteroaromatic, or unsaturated compounds and groups, eachcapable of contributing 2 to 24 pi-electrons to the valence shell of M′;

L⁴ represents none or 1 to 24 ligands that can be the same or different,each contributing 2, 4, or 6 electrons selected from mono-, di-, andtridentate ligands to the valence shell of M′;

L⁵ represents none or 1 to 12 ligands that can be the same or different,each contributing no more than one electron to the valence shell of eachM′;

M′ represents from 1 to 6 of the same or different metal atoms selectedfrom Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, Fe, Ru, Os, Co, Rh,Ir, Ni, Pd, and Pt which are commonly referred to as the transitionmetals;

e′ is an integer from 0 to 2 such that the organometallic portion of themolecule is neutral, cationic, or dicatioiiic;

X′ is an anion selected from organic sulfonate and halogenated,alkylated, or arylated metal or metalloid groups;

f is an integer from 0 to 2 and is the number of anions required tobalance the charge e on tile organomiietallic portion of the molecule;

with the proviso that the organometallic compound contains at least onetransition metal to carbon bond and that L³, L⁴, L⁵, M′, e′, X′, and fare chosen so as to achieve stable electioniic configuiration.

Illustrative exiainples of L³ include ethylene, cyclohexane, acetylene,eta⁵-cyclopentadieniyl, cyclooctadiene, benzene, and pyrene.Illustrative examples of L⁴ include carbon monoxide, triphenylphosphine,acetonitrile, and 1,2-bis(diphenylphosphino)ethane. Illustrativeexamples of L⁵ include methyl, vinyl, triphenyl tin, and actyl groups.Illustrative examples of X′ include CF₃SO₃ ⁻, (C₆H₅)₄B⁻, BF₄ ⁻, PF₆ ⁻,AsF₆ ⁻, SbF₆ ⁻, and SbF₅OH⁻.

Useful organometzillic curing agents have been more completely describedin U.S. Pat. No. 5,215,860 (incorporated herein by reference).

Preferred examples of catailysts for cyanate ester cure include, but arenot limited to: (CpFe(CO)₂)₂, Mn₂(CO)₁₀, (MeCpMo(CO)₃)₂,(CpFe(xylene))(SbF₆), (CpFe(cumene))(PF₆), MeCpMn(CO)₃, CpFe(CO)₂Cl,(benzene)Cr(CO)₃, Cp₂TiCl₂, MeCpMn(CO)₂PPh₃, Mn(CO)₅Br,(MeCpMn(CO)₂NO)PF₆ and (anisole)Cr(CO)₃. Cp=eta⁵-C₅H₅, Me=methyl, andPh=phenyl.

Organometallic compounds useful in the practice of the present inventionare available from Strem Chemical Co. (Newburyport, Mass.) or can beprepared by literature methods known to those skilled in the art. Seefor example Dictionary of Orginometallic Compounds (Chapman and HillLtd. 1984); Comprehensive Organonietallic Chemistry, The Synthesis,Reactions and Structures of Organometicllic Compounds (Pergamon 1982).

The organometallic compounds can be present in a catalytically effectiveamount, preferably in the range of 0.01 to 20, most preferably 0.1 to 5,parts by weight (pbw) based on 100 parts of the energy-polymerizablecomposition. In some applications it may be desirable to sorb theorganometallic compound onto an inert support such as silica, alumina,clays, etc., as described in U.S. Pat. No. 4,677,137.

The first phase can be present in the range of 30 to 99, preferably 50to 90, and most preferably 70 to 80 percent by weight, and the secondphase can be present in a range (weight percent) of 1 to 70, preferably10 to 50, and more preferably 20 to 30 of the total network.

The IPN or semi-IPN ol the invention can also contain additives,adjuvants, fillers, stabilizers, and the like, so long as such materialsdo not interfere with formation of the IPN or semi-IPN and are notdeleterious to the functions thereof. Stabilizers against thermal and UVdegradation can include o-hydroxybenzophenones, cyanoacrylate esters,2-(o(-hydroxyphellyl)belizotilizoles, hinedered aminie light stabilizers(HALS), copolymerizable UJV absorbers anti the like. Iurtlier additivescan include fillers, such as fumed silica, hydrophobic silica (U.S. Pat.Nos. 4,710,536 and 4,749,590), alumina, and natural and synthetic resinsin particulate, flake or fibrous form. For various appllications,foaming agents, such as low-boiling hydrocarbons; fluorinated materials;colorants, dyes and pigments; flame-retardants; anti-static agents;flow-control agents; and coupling agents for additives, such as silanes,may be added. When additives are present, they are added in amountsconsistent with the known functional uses of such additives.

It is also within the scope of this invention to add optional adjuvantssuch as thixotropic agents; plasticizers; toughening agents such asthose taught in U.S. Pat. No. 4,846,905; antioxidants; flow agents;flatting agents; binders; blowing agents; fungicides; bactericides;surfactants; glass and ceramic beads; and reinforcing materials, such aswoven and nonwoven webs of organic and inorganic fibers, such aspolyester, polyimide, glass fibers and ceramic fibers; and otheradditives as known to those skilled in the art can be added to thecompositions of this invention. These can be added in an amounteffective for their intended purpose; typically, amounts up to about 50parts of adjuvant per total weight of formulation can be used.

Dyes that are useful in the present invention include those having afluorescent dye group that can be covalently bound to the polymer of thesecond phase and/or those that are soluble in the polymer of the secondphase.

It has been found to be advantageous to attach a dye to a polymer matrixto slow migration of the dye and to enhance dye compatibility. Forexample, a common fluorescent yellow green dye, CI Solvent Yellow 98(SY98, Hoescht Celanese, Charlotte, N.C.), designated by formula V,having the structural formula

lends itself to simple structural modification through the anhydrideprecursor. Hydroxy and (meth)acrylate functional dyes that aremodifications of CI Solvent Yellow 98 have been prepared. A hydroxyfunctional dye, designated YGOH (VI), which can be converted to anacrylate functional dye, designated YGOAc (VII), has been reacted into aurethane, and the acrylate functional dye was incorporated into a chaingrowth polymer. In this way, the rate of dye migration out of thesematrices was slowed. The dyes have the formulae

and were prepared by reaction of the corresponding anhydride with theappropriate hydroxy functional primary amine to form, e.g., the hydroxyfunctional imide VI, from which acrylate VII can be prepared by knownmethods.

Fluorescent dyes useful in the present invention include dyes from thethioxanthene, xanthene, perylene, perylene imide, coumarin,thioindigoid, naphthalimide and methine dye classes. Useful dye classeshave been more completely described in U.S. Pat. No. 5,674,622(incorporated herein by reference). Representative fluorescent dyeexamples include, but are not limited to: Lumogen F Orange™ 240 (BASF,Rensselaer, N.Y.); Lumogen F Yellow™ 083 (BASF, Rensselaer, N.Y.);Hostasol Yellow™ 3G (Hoechst-Celanese, Somerville, N.J.); Oraset Yellow™8GF (Ciba-Geigy, Hawthorne, N.Y.); Fluorol 088™ (BASF, Rensselaer,N.Y.); Thermoplast F Yellow™ 084 (BASF, Rensselaer, N.Y.); GoldenYellow™ D-304 (DayGlo, Cleveland, Ohio); Mohawk Yellow™ D-299 (DayGlo,Cleveland, Ohio); Potomac Yellow™ D-838 (DayGlo, Cleveland, Ohio) andPolyfast Brilliant Red™ 5B (Keystone, Chicago, Ill.).

In a preferred embodiment the fluorescent dyes of the invention are dyesfrom the thioxanthene and perylene imide classes of compounds. A singlefluorescent dye may be used to color an article of the invention or acombination of one or more fluorescent dyes and one or more conventionalcolorants may be used.

Typically, between about 0.01 and about 2.00 weight percent, andpreferably between about 0.05 and about 0.70 weight percent, and mostpreferably between about 0.1 and about 0.5 weight percent of fluorescentdye (based on total composition) is contained in the article of thepresent invention. It will be understood that articles with dye loadingsoutside this range can be used in accordance with the invention.Although dye loading may vary depending upon the final application,these loadings are typical for about a 0.075 to 0.25 mm thick film.However, if the dye is added to a thicker film, lower dye loadings cangive the same visual effect. As known by those skilled in the art,articles having heavier dye loadings will exhibit brighter fluorescenceand/or deeper color than will articles with lighter dye loadings of thesame dye. However, articles having very high fluorescent dye loadingsmay exhibit a self-quenching phenomenon which occurs when molecules ofthe fluorescent dye absorb the energy emitted by neighboring fluorescentdye molecules. This self-quenching causes an undesirable decrease influorescent brightness.

In some embodiments, the fluorescent dye in the articles of the presentinvention will consist essentially of one or more dyes selected from theperylene imide and thioxanthene classes of compounds. In otherinstances, the article may also contain other coloring agents such aspigments or other dyes in addition to those described to adjust thecolor and appearance of the article. For example, polycarbonatetypically has a yellow cast. Minor amounts, e.g., about 0.01 weightpercent or less, of pigments sometimes referred to as “bluing agents”may be incorporated to neutralize the yellow appearance. Othernon-fluorescent or conventional dyes or pigments may also be added tothe present invention. However, care should be taken in selecting suchdyes and dye loadings so that the dyes do not significantly interferewith the performance of the fluorescent dyes. If retroreflectiveelements are included in the article of the present invention, any dyesor pigments should not undesirably impair the transparency of thearticle is such would impair the retroreflective properties of thearticle.

It is within the scope of the present invention to use a conventionaldye instead of a fluorescent dye in the IPN or semi-IPN of theinvention. Examples of nonfluorescent dye classes that can be used inthe present invention include azo, heterocyclic azo, anthraquinone,benzodifuranone, polycyclic aromatic carbonyl, indigoid, polymethine,styryl, di- and tri-aryl carbonium, phthalocyanines, quinophtlialones,sulfur, nitro and nitroso, stilbene, and formazan dyes. Theconcentration of dye needed is specific to each application. However,typically between about 0.01 and about 5.00 weight percent andpreferably between about 0.05 and about 2.00 weight percent and mostpreferably between about 0.1 and 1.00 weight percent of regular dye(based on total composition) is contained in the article of the presentinvention. It will be understood that articles with dye loadings outsidethis range can be used in accordance with this invention.

Hindered amine light stabilizers (HALS) can be included in thecompositions of the present invention.

Without intending to be bound by theory, it is believed that thecombination of the sterically hindered amine, the IPN or semi-IPN matrixand the fluorescent dye in the present invention prevents or lessensdegradation and/or reaction between the dye and the matrix which couldotherwise occur. Insofar as we know, the advantages of the presentinvention are attained through the combination of dye, polymer matrixmaterial, and hindered amine light stabilizer described herein. The dyesin the present invention are thought to act as singlet oxygensensitizers. Energy transfer, which generally occurs from the tripletstate of the dye, is quenched by ground state molecular oxygen toproduce active singlet oxygen. The singlet oxygen is then free to reactwith the dye, causing dye degradation. Alternatively, the singlet oxygenmay react with the polymer, leading to degradation of the IPN orsemi-IPN. However, the hindered amine light stabilizer present in theinvention is capable of directly quenching the singlet oxygen formed,preventing initiation of the degradation reactions. The hindered aminelight stabilizers can also prevent secondary reactions initiated bypolymer oxidation from procceeling. These reactions include a number ofradical or peroxide-based chain reactions that are thought to occur inthe photo-oxidation of polymers which can result in polymer and dyedegradation. Preventing these reactions increases the durability of thepolymers and the dye in the dyed system.

Any hindered amine light stabilizer can be suitable for the presentinvention and include 2,2,6,6-tetraalkyl piperidine compounds, butpreferably 2,2,6,6-tetramethyl piperidine compounds are employed as thehindered amine light stabilizers due to the ready availability of thecompounds. Preferred stabilizers include:

1) Dimethyl succinate polymer with4-hydroxy-2,2,6,6-tetramethyl-1-piperidine ethanol available as Tinuvin™622 from Ciba-Geigy Corp., Flawthorne, N.Y.;

2) Poly(6((1,1,3,3-tetramethybutyl)amino)-s-triazine-2,4-diyl)(2,2,6,6-tetramethyl-4-piperidyl)imino)hexamethylene((2,2,6,6-teramethyl-4-piperidyl)imino)) available as Chimassorb™ 944FL(Ciba-Geigy Corp., Ardsley, N.Y.); and

3) bis(2,2,6,6-tetramethyl-4-piperidinyl)sebacate available as Tinuvin™770 from Ciba-Geigy Corp.

4) bis(2,2,6,6-tetramethyl-1-octyloxy-4-piperidinyl sebacate) (Tinuvin™123 from Ciba-Geigy Corp.).

The hindered amine light stabilizers are included in articles of thepresent invention from about 0.05 to about 3.00 weight percent andpreferably from about 0.10 to about 2.00 weight percent and mostpreferably from about 0.1 to about 1.0 weight percent. Pavement markings(e.g., paint, raised markings, tape) having enhanced daytime visibilitycan be made incorporating IPNs or semi-IPNs of the invention. Pavementmarkings typically comprise selected distinctive color(s) so as to makethem visible under ambient daytime lighting conditions to effectivelyguide and signal a motorist. Then markings typically contain hidingpigments (e.g. titanium dioxide) to aid in obtaining contrast with thepavement. Night visibility is typically obtained by incorporatingretroreflective elements (e.g. glass beads or microspheres) into themarking. To improve the daytime performance, the use of lltiorescingcolorants has been suggested as discussed in U.S. Pat. No. 3,253,146 toimprove performance under daytime conditions of poor visibility, such asat dusk and on overcast days.

A construction utilizing a transparent fluorescent layer over a white ortinted substrate would give the best performance because mixing hidingpigments into a fluorescent layer can substantially kill the fluorescenteffect. Laminated constructions of the invention are particularlypreferred because of enhanced visibility and improved durability.Improved nighttime performance can be achieved by incorporating glassmicrospheres in the top layer of the construction.

IPNs and semi-IPNs of the present invention find use as fibers, fabrics,canvas markings, roll-up signs, barrel wraps, cone sleeves, truckmarkings, license plates, safety vests, pavement marking paints andtapes, reflective films, and other articles where flexible materialshaving dye durability are desired. These materials preferably arefluorescent. The materials of the present invention are particularlyuseful in safety applications and devices, such as in fluorescenttraffic signs, where dye stability and durability are highly valued.

Objects and adv(art(ges of the invention are further illustrated by thefollowing examples, but the particular materials and amounts thereofrecited in these examples, as well as other conditions and details,should not be construed to unduly limit this invention. Unless otherwisestated, all parts are parts by weight and all temperatures are degreescentigrade.

In the examples, below, non-fluorescent dyes can be substituted forfluorescent dyes.

In the examples the following evaluation methods were used:

Weathering Studies. The films prepared in the Examples were exposed to awater cooled Xenon Arc device (6500 Watt Xenon Burner filtered byborosilicate inner and outer filters, Model 65WWR, Atlas ElectricDevices Co., Chicago, Ill.) according to ASTM standard G-26-96 Type B,BH. The amount of fluorescent dye retained in the sample was determinedby measuring the major dye absorption band (456 nm) before and afterweathering using UV-Vis spectroscopy. Following Beer's Law, a decreasein absorbance is related to a reduction in dye concentrationl. ForExamples 1A-1F and 5A-5E, a “percent fluorescent dye retention” valuewas calculated as the ratio of the peak absorbance in the weatheredsample to the peak absorbance of the original unweathered sample. Asimilar “percent fluorescent dye retention” value was calculated forExamples 2A-F, 6, 7, and 9. However, for these examples the value wascalculated as the ratio of the area under the absorbance peak in theweathered sample to the area under the absorbance peak of the originalunweathered sample.

Migration Studies. Migration studies were conducted to confirm that thedye had become covalently attached to the network. Three layers of clearMorthane PNO3 polyurethane film (aliphatic polyester polyurethane withadded UV absorber, Morton International, Inc., Chicago, Ill.) werestacked on top of the fluorescent films, sandwiched between twopolyethylene terephthalate (PET) liners (51 μm) and placed in a press at221 KPa (32 psi) for 72 hrs at 23° C. and 24 hours at 66° C. Movemenntof the dye into the clear layers indicated unattached dye. A “% dyeretention after migration” value was calculated as the ratio of the peakabsorbance after exposure to the peak absorbance prior to exposure asdescribed in Weathering Studies, above.

Dye Extraction Studies. Dye extraction studies were also conducted toevaluate dye attachment to the IPN. IPN films comprising either thenonfunctional fluorescent dye, SY98, or one of the functionalfluorescent dyes, YGOH or YGOAc, were placed in refluxingtetrahydrofuran (THF) for 24 hours, removed, and then dried at 20-23° C.for 72 hours. The amount of dye retained by the films was calculatedusing UV-V is as described in Weathering Studies, above.

Dynamic Mechanical Analysis (DMA). Dynamic mechanical analysis wasperformed on the samples using a Seiko DMS200 Tension Module calibratedwith a polycarbonate standard (Seiko Instniments Inc., Sunnyvale,Calif.). The sample dimensions were set according to the instrumentrequirements, and were typically 15 mm long by 6.35 mm wide, thefrequency was 1 Hz and the heating rate was 2° C./min. The reported Tgvalues were taken as the peak of the tan delta curve.

Tensile Testing. Tensile properties were determined using an InstronModel 1122 with Series IX software (Instron Corp., Park Ridge, Ill.). Aminimum of 5 specimens were tested for each sample. The specimen widthwas 1.24 cm (0.5 inches), the gap separation was 5.08 cm (2 inches) andrate of strain was 15.24 cm/min (6 inches/minute). Results are presentedas the average of five specimens.

Fluorescence. In the present invention, fluorescence was measured usinga SLM AB2 Luminescence Spectrophotometer (SLM Instruments, Rochester,N.Y.) using a 150 watt continuous Xenon lamp.

Retained fluorescence was calculated as the ratio, in percent, offluorescent intensity of the sample after exposure to weathering for theindicated length of time to the fluorescent intensity of an unexposedsample, at the wavelength of peak emission of the unexposed sample.

EXAMPLE 1 Effect of Dye Placement and Aromaticity and an Example of aCrosslinked Urethane Continuous Phase and an Acrylate Dispersed Phase

The unique interpenetrating polymer network (IPN) feature of microphaseseparated domains provides a mechanism to control the placement of thefluorescent dye into only one of the two domains and to control thechemical nature of the dye microenvironment within each domain. In oneset of examples (1A-D), the dye was placed in the urethane domain byreacting the hydroxyl functional dye into the urethane network. In asecond set of examples (1E-H), the dye was placed in the acrylate domainby copolymerizing the acrylate functional dye into the acrylate network.The nature of the dye microenvironment was varied by changing thearomatic vs. aliphatic content of each of the two networks. Controllingthe level of aromaticity around the dye allowed investigation of theeffect of dye environment on dye stability. The samples were weatheredaccording to ASTM G-26-96 in the xenon arc device for 232 hours and thenanalyzed for percent peak retention as described above in the WeatheringStudies section. The sample preparation is described below while theweathering results are shown in Table 1.

EXAMPLE 1A

In a 100 mL plastic beaker, 13.63 g phenoxyethyl acrylate (POEA,Sartomer™ SR339, Sartomer Co., Exton, Pa.) containing 0.125 g dissolvedYGOH dye (structure VI), 1.48 g isocyanurate-containing polyisocyanate(Desmodur N-3300™, Bayer Chemicals, Pittsburgh, Pa.) and 0.015 gdibutyltin dilaurate catalyst (DBTDL, Aldrich Chemical Co., Milwaukee,Wis.) was combined with a solution of 3.00 g POEA containing 0.35 gdissolved di-(4-t-butylcyclohexyl)peroxydicarbonate thermal free-radicalinitiator (Perkadox™ 16, Akzo Nobel Chemicals Inc., Stratford, Conn.),1.00 g caprolactone acrylate (Sartomer™ SR 495), 0.05 g BYK-066™ flowcontrol agent (BYK-Chemie, Wallingford, Conn.), 15.01 g ethoxylatedBisphenol A polyol (Synfac 8024™, Milliken Chemical, Spartanburg, S.C.),0.88 g ethoxylated bisphenol A diacrylate, (EBAD, Sartomer™ SR 349),0.38 g Uvinul N-3039™ UV stabilizer (BASF Corporation, Rensselaer, N.Y.)and 0.50 g Tinuvin 123™ hindered amine light stabilizer (Ciba-GeigyCorp., Ardsley, N.Y.). The solution was mixed with a spatula, treatedwith 16.01 g of Desmodur N-3300™ isocyanurate-containing polyisocyanate,agitated with an air mixer for 1 minute and degassed under vacuum (500mm Hg) for 3 minutes. The solution was knife coated between two 15.2 cmwide silicone-coated PET release liners (102 μm thick, CourtauldsAerospace, Inc., Glendale, Calif.) at a thickness of 102 μm, cured witha temperature ramp from 70° C. to 120° C. (2.5° C./min) and postcured at90° C. for 16-17 hours.

EXAMPLE 1B

An IPN was prepared as described in Example IA, except that 0.25 gPerkadox™ 16 was used, 18.06 g caprolactone polyol (Tone™ 201, UnionCarbide Corp., Danbury, Conn.) was used in place of the Synfac 8024polyol, and in the final mixing step, 12.97 g of Desmodur N-3300 wasused.

EXAMPLE 1C

An IPN was prepared as described in Example 1A, except that 13.63 gtetrahydrofurfuryl acrylate, (THFA, Sartomer™ SR285, Sartomer ChemicalCo., Exton, Pa.) was used in place of POEA.

EXAMPLE 1D

An IPN was prepared as described in Example 1B, except that 13.63 g THFAwas used in place of POEA.

EXAMPLE 1E

An IPN film was prepared as described in Example 1 except that: YGOAcdye (structure VII) was used in place of YGOH dye; no Desmodur N-3300isocyanate was used in the initial mix; 0.0075 g DBTDL was used; and17.49 g Desmodur N-3300 isocyanate was used in the final mix.

EXAMPLE 1F

An IPN was prepared as described in Example 1E, except that 0.25 gPerkadox 16 initiator was used and 18.06 g Tone 201 polyol was used inplace of Synfac 8024 polyol.

EXAMPLE 1G

An IPN was prepared as described in Example 1E, except that 13.63 g THFAwas used in place of POEA.

EXAMPLE 1H

An IPN was prepared as described in Example 1F, except that 13.63 g THFAwas used in place of POEA.

TABLE 1 Data for Example 1: Effect of Changing the Local Dye Environmenton Dye Durability % Dye Retained after 232 Hours Example Dye PolyolAcrylate Weathering 1A* YGOH Synfac 8024 EBAD/POEA (5/95) 31 1B* YGOHTone 201 EBAD/POEA (5/95) 32 1C* YGOH Synfac 8024 HDDA/THFA (5/95) 181D* YGOH Tone 201 HDDA/THFA (5/95) 17 1E  YGOAc Synfac 8024 EBAD/POEA(5/95) 70 1F  YGOAc Tone 201 EBAD/POEA (5/95) 74 1G  YGOAc Synfac 8024HDDA/THFA (5/95) 41 1H  YGOAc Tone 201 HDDA/THFA (5/95) 28 *Comparative:Dye in first phase

The data in Table 1 show that for this combination of a crosslinkedurethane for the continuous phase and a crosslinked acrylate for thesecond phase, the dye was more durable when it was located in the secondphase. The dye retention of the crosslinked films was increased by usingaromatic second phases which is believed to oxidize sacrificiallythereby protecting the fluorescent dye. Adding aromatic components tothe first phase did not significantly affect the dye retention. Insummary, it appeared that the best dye durability was achieved when theacrylate fluorescent dye was placed in a dispersed aromatic acrylatephase as shown in Examples 1E and 1F while the continuous urethane phasecould be either aromatic or aliphatic since the composition of theurethane phase had little influence on the overall weathering.

The results from Example 1 indicate that fluorescence durability wascontrolled through the second phase material, leaving the first orcontinuous phase material to provide the desired mechanical properties.Therefore, these results indicated that the dye durability and thephysical properties of the material were independently controlled.

EXAMPLE 2 Demonstration of Different Continuous and Dispersed Phases

2A-1. EMAA/Acrylatc with YGOAc

In this example a semi-IPN was prepared with an ethylene-methacrylicacid copolymer, EMAA (Nticrel 699T

, DuPont Chemicals, Wilmington, Del.) and monofunctional anddifunctional acrylate monomers. Weathering additives were added to helpprotect both the dye and polymer. A photoinitiator comprising a 1:1mixture of 2,4,6-trimethylbenzoyl diphenyl phosphine oxide and2-methyl-2-hydroxypropriophenone (Darocur™ 4265, Ciba-Geigy Corp.,Tarrytown, N.Y.) was added and the resulting films were cured using aSylvania 350BL UV lamp (Siemens Corp./Osram Sylvania Inc,. Danvers,Mass.). The dye used was YGOAc (structure VII).

To 21.17 g of a Nucrel 699 polymer melt prepared in a 160° C. Brabendermixing head at 50 rpm (C. W. Brabender Instruments, Inc., SouthHackensack, N.J.) and cooled to 150° C., 0.27 g Tinuvin™ 770 hinderedamine light stabilizer (Ciba-Geigy Corp.); 0.27 g Chimassorb™ 944hindered amine light stabilizer (Ciba-Geigy Corp.); 0.27 g Darocur 4265photoinitiator; 0.28 g ethoxylated bisphenol A diacrylate; and 0.039 gYGOAc dissolved in 5.00 g POEA were added. After the final addition,mixing continued for five minutes at 150° C. (100 rpm). The mixture wasremoved and pressed between 102 μm (4 mil) polyethylene terephthalate(PET)-silicone release liners into films using a platen press at 208 MPa(30,000 psi) heated to 110° C., then cured for 15 minutes on each sidesimultaneously using Sylvania 350BL bulbs.

Finally, the sample was analyzed by fluorescent confocal microscopy. Thedispersed acrylate phase was fluorescent while the continuous phase wasnot, which indicated that the acrylate functional fluorescent dyecovalently attached to the acrylate phase.

2A-2. EMAA with YGOAc (Comparative)

In this example an LMAA film was prepared as described in Example 2A-1,except that mono- and di-functional acrylates were not added. Also,26.70 g of Nucrel 699 was used. Since there were no acrylate monomersused, the photoinitiator and the final UV cure step were omitted.

2B-1. Polurethane (PU)/Acrylate with YGOAc

In this example a semi-IPN was prepared with an aliphatic polyesterpolyurethane, PU, Morthane 1,424.167 (Morton International Inc.,Chicago, Ill.) and mono- and di-functional acrylate monomers.

To 19.04 g of a Morthane L424.167 polymer melt prepared in a 155° C.Brabender mixing head (50 rpm) were added 0.24 g Tinuvin 622; 0.045 gfluorescent dye YGOAc; 0.27 g Darocur 4265; 0.28 g EBAD; and 4.65 gPOEA. After the final addition, mixing continued for five minutes at155° C. and 100 rpm. The mixture was removed and pressed between 102 μmPET-silicone release liners into films using a platen press at 172 MPa(25,000 psi) heated to 120° C. and then cured for 15 minutes on eachside simultaneously using Sylvania 350BL UV bulbs.

2B-2. Polyurethane (PU)/Epoxy with YGOH

In this example a semi-IPN was prepared, using Mothane L424.167 and adifunctional epoxy monomer (Epon™ 828, Shell Chemicals, Houston, Tex.).Weathering additives were added to help protect both the dye andpolymer.

To 21.16 g of a Morthane L424.167 polymer melt prepared in a 150° C.Brabender mixing head (50 rpm) were added 0.27 g Tinuvin 770; 0.27 gChimassorb 944; 0.034 g fluorescent dye YGOH; and 0.11 gtriphenylsulfonium hexafluoroantimonate photoinitiator (see U.S. Pat.No. 4,256,828, Example 37) dissolved in 5.43 Epon™ 828. After the finaladdition, mixing continued for five minutes at 150° C. and 100 rpm. Themixture was removed and pressed between 102 μm PET-silicone releaseliners into films using a platen press at 208 MPa heated to 150° C. andthen passed under the medium pressure mercury UV lamp (AmericanUltraViolet Co., Murray Hill, N.J.) twice at a setting of 118 W/cm and aspeed of 6.1 m/min. to yield a dose of 0.56 J/cm² per pass. After the UVexposure the sample was heated at 120° C. for 30 minutes.

2B-3. Polyurethane/Cyanate Ester with YGOH

A semi-IPN film was prepared from an aliphatic polyester polyurethaneand a difunctional cyanate ester monomer (AroCy™ B-10, Ciba-Geigy Corp.,Ardsley, N.Y.). Weathering additives were added to help protect both thedye and polymer, and the resulting films were cured using a mediumpressure mercury UV lamp (American UltraViolet Co., Murray Hill, N.J.)followed by heating.

To 20.87 g of a Morthane L424. 167 polymer melt prepared in a 150° C.Brabender mixing head (50 rpm) were added 0.26 g Tinuvin 770; 0.26 gChimassorb 944; 0.024 g YGOH; and a solution of 0.08 g(1-methyl-2,4-cyclopentadien-1-yl)-manganese tricarbonyl catalyst(Aldrich Chemical Company, Milwaukee, Wis.) dissolved in 3.80 g AroCy™B-10. After the final addition, mixing continued for five minutes at150° C. and 100 rpm. The mixture was removed and pressed between two 51μm untreated PET liners into films using a platen press at 208 MPaheated to 150° C. One of the liners was removed, and the sample waspassed under the medium pressure mercury UV lamp on a setting of 1 18W/cm and a speed of 6.1 m/min. to yield a dose of 0.71 J/cm². After theUV exposure, the sample was heated at 130° C. for 30 minutes.

2C-1. EAA/Acrylate with YGOAc

In this example a semi-IPN was prepared with an ethylene-acrylic acidcopolymer (EAA, Primacor™ 3440, Dow Chemical Co., Midland, Mich.) andmono- and di-functional acrylate monomers. Weathering additives wereadded to help protect both the dye and polymer.

To 20.70 g of a EAA polymer melt prepared in a 150° C. Brabender mixinghead at 50 rpm, 0.26 g Tinuvin 770; 0.26 g Chimassorb 944; 0.26 gDarocur 4265 photoinitiator; 0.26 g EBAD; and 0.038 g YGOAc dissolved in4.90 g POEA were added. After the final addition, mixing continued forfive minutes at 150° C. (100 rpm). The mixture was removed and pressedbetween 102 μm PET-silicone release liners into films using a platenpress at 208 MPa heated to 150° C., then cured for 15 minutes on eachside simultaneously using Sylvania 350BL UV bulbs.

2C-2. EAA with YGOAc (Comparative)

A film was prepar from an EAA polymer and fluorescent dye YGOAc in theabsence of additional acrylate monomers.

To 26.12 g of EAA polymer melt (Primacor 3440) prepared in a 150° C.Brabender mixing head at 50 rpm, 0.26 g Tinuvin 770; 0.26 g Chimassorb944 and 0.038 g YGOAc were added. After the final addition, mixingcontinued for five minutes at 150° C. (100 rpm). The mixture was removedand pressed between 102 μm PET-silicone release liners into films usinga platen press at 208 MPa heated to 150° C.

2D-1. LDPE/Acrylate with YGOAc

A semi-IPN film was prepared from a low density polyethylene, LDPE, (Dow4012™, Dow Chemical Co., Midland, Mich.) and mono- and di-functionalacrylate monomers. Weathering additives were added to help protect boththe dye and polymer.

To 21.16 g of a Dow 4012 polymer melt prepared in a 185° C. Brabendermixing head at 50 rpm and cooled to 151° C. were added 0.27 g Tinuvin770; 0.27 g Chimassorb 944; 0.27 g Darocur 4265; 0.27 g EBAD; 0.039 gYGOAc and 5.00 g POEA. After the final addition, mixing continued forfive minutes at 151° C. (100 rpm). The mixture was removed and pressedbetween 102 μm PET-silicone release liners into films using a platenpress at 208 MPa heated to 130° C., then cured for 15 minutes on eachside simultaneously using a Sylvania 350BL UV bulb.

2D-2. LDPE with YGOAc (Comparative)

An LDPE film was prepared using only Dow 4012 LDPE and fluorescent dyeYGOAc.

To 26.70 g of a Dow 4012 polymer melt prepared in a 185° C. Brabendermixing head at 50 rpm were added 0.27 g Tinuvin 770; 0.27 g Chimassorb944 and 0.039 g of fluorescent (lye YCGOAc. After the final addition,mixing continued for five minutes at 185° C. (100 rpm). The mixture wasremoved and pressed between 102 μm PET-silicoic release liners intofilms using a platen press at 208 MPa heated to 170° C.

2E-1. PVC/Acrylate with YGOAc

A semi-IPN film was prepared from polyvinyl chloride polymer, PVC,(Formula S00354, Alpha Chemical and Plastics Corporation, Pineville,N.C.) and mono- and di-functional acrylate monomers. The PVC used was aplasticized formula containing flame retardant, fungicide, thermalstabilizers and costabilizers, lubricant and processing aids,benzophenone UV absorber and optical brightener. Additional weatheringadditives were added to this formulation to help protect both the dyeand polymer.

To 24.65 g of the PVC polymer melt prepared in a 180° C. Brabendermixing head at 50 rpm and cooled to 150° C. were added 0.23 g Tinuvin770; 0.23 g Chimassorb 944; 0.23 g Darocur 4265; 0.23 g EBAD; and 0.033g YGOAc dissolved in 4.25 g POEA. After the final addition, mixingcontinued for five minutes at 150° C. (100 rpm). The mixture was removedand pressed between 102 μm PET-siliconie release liners into films usinga platen press at 208 MPa heated to 180° C., then cured for 15 minuteson each side simultaneously using a Sylvania 350BL UV bulb.

2E-2. PVC with VGOAc (Comparative)

In this example a IIVC film was prepared with a polyvinyl chloridepolymer, PVC, (formula S00354 from Alpha Chemical and PlasticsCorporation, Pineville, N.C.) and an acrylate functional fluorescent dye(YGOAc, see structure VII), without added acrylate monomers.

To 29.62 g of the PVC polymer melt prepared in 180° C. Brabender mixinghead at 50 rpm )0.23 g Tinuvin 770; 0.23 g Chimassorb; and 0.033 g YGOAcwere added. After the final addition, mixing continued for five minutesat 180° C.(100 rpm). The mixture was removed and pressed between 102 μmpolyethylene terephthalate (PET)-silicone release liners into filmsusing a platen press at 208 Mpa (30,000 psi) heated to 150° C.

2F-1. S-I-S/Acrylatc with YGOAc

A semi-IPN film was prepared with a styrene-isopretie-styrene (S-I-S)block copolymer (Kraton™ D1107, Shell Chemical Co., Naperville, Ill.)and mono- and di-functional acrylate monomers. Weathering additives wereadded to help protect both the dye and polymer.

To 21.16 g of a Kraton D1107 polymer melt prepared in a 185° C.Brabender mixing head at 50 rpm and cooled to 154° C. were added 0.27 gTinuvin 770; 0.27 g Chimassorb 944; 0.27 g Darocur 4265; 0.27 g EBAD;0.039 g YGOAc and 5.10 g POEA. After the final addition, mixingcontinued for five minutes at 154° C. (100 rpm). The mixture was removedand pressed between 102 μm PET-silicone release liners into films usinga platen press at 208 MPa heated to 130° C., then cured for 15 minuteson each side simultaneously using a Sylvania 350BL UV bulb.

2F-2. S-I-S with YGOAc (Comparative)

An elastomeric film was prepared from Kraton D1107 YGOAc fluorescentdye, without added acrylate monomers.

To 26.72 g of a Kraton D1107 polymer melt prepared in a 185° C.Brabender mixing head at 50 rpm were added 0.27 g Tinuvin 770; 0.27 gChimassorb 944; and 0.041 g YGOAc. After the final addition, mixingcontinued for five minutes at 185° C. (100 rpm). The mixture was removedand pressed between 102 μm PET-silicone release liners into films usinga platen press at 208 MPa heated to 170° C.

Table 2, below, summaries Examples 2A-1 through 2F-2 with respect to thecontinuous phase composition, the dispersed phase composition, the typeof dye and weight percent dye used in the overall composition, thethickness of the film, and the effect on fluorescent dye durability ofadding various fluorescent dyes to resins with and without a dispersedphase when subjected to accelerated weathering.

TABLE 2 Formulations and Percent Fluorescent Dye Retention AfterAccelerated Weathering First Second Wt % Film 50 100 150 200 300 Ex. #Phase Phase Dye Dye Thickness (mm) hours hours hours hours hours 2A-1EMAA Acrylate YGOAc 0.14 0.18 54 2A-2* EMAA None YGOAc 0.14 0.19  9 2B-1PU Acrylate YGOAc 0.18 0.09 77 2B-2 PU Epoxy YGOH 0.12 0.15 87 632B-3^(..) PU Cyanate Ester YGOH 0.12 0.19 87 69 2C-1 EAA Acrylate YGOAc0.14 0.23 39 2C-2* EAA None YGOAc 0.14 0.24 13 2D-1 LDPE Acrylate YGOAc0.14 0.18 59 2D-2* LDPE None YGOAc 0.14 0.15 50 2E-1 PVC Acrylate YGOAc0.11 0.14 83 72 63 2E-2* PVC None YGOAc 0.11 0.13 81 66 54 2F-1^(†)S-I-S Acrylate YGOAc 0.14 0.17 40 29 2F-2*^(†) S-I-S None YGOAc 0.140.13 34 10 *Comparative ^(..)Cured onto an 51 μm (2.0 mil) untreated PETliner. The liner remained in place during weathering ^(†)Laminatedbetween two 51 μm (2.0 mil) untreated PET liners before weathering.These liners remained in place during weathering.

The data in Table 2 show that adding a dispersed second phase containinga fluorescent dye to a polymeric continuous phase provided goodfluorescent dye retention and enhanced fluorescent dye durability onexposure to accelerated weathering compared to samples without adispersed second phase. This point was demonstrated for example, whencomparing examples 2A-1 with 2A-2; 2C-1 with 2C-2; 2D-1 with 2D-2; 2E-1with 2E-2; and 2F-1 with 2F-2. In each of these cases, the sample withthe addition of a second phase retained more fluorescent color after aspecified period of time compared to the sample without the secondphase.

EXAMPLE 3 Preventing Dye Migralion

To overcome the common loss mechanism of dye migration in flexiblematrices, functionalized fluorescent dyes (YGOH and YGOAc) were reactedinto the urethane or acrylate components of the IPN respectively. Dyemigration and extraction studies were conduicted according to abovecited methods. The results from the migration studies are shown in Table3 as % Dye Retention after Migration. This number refers to the percentof fluorescent dye that remained in the original film after themigration study was complete. The remaining dye had migrated to theother clear sheets. The results of the extraction studies are shown inTable 3, below, as % Dye Retention after Extraction.

EXAMPLE 3A

In a 100 mL plastic beaker, 23.87 g of polyol KM-10-1733™ (availablefrom Stahl USA, Peabody, Mass.) containing 0.13 g dissolved SY98 dye,(structure V) was combined with a solution of 3.75 g THFA, containing0.125 g Perkadox™ 16 and 0.05 g BYK-066™, a solution of 3.75 gpropoxylated neopentyl glycol diacrylate, (Sartomer™ SR 9003, SartomerCompany, Inc.) containing 0.0075 g DBTDL, 7.5 g isooctyl acrylate (IOA,3M, St. Paul, Minn.), and 1.00 g caprolactone acrylate. The solution wasmixed with a spatula, treated with 11.23 g of an aliphaticpolyisocyanate (Desmodur N-100™, Bayer Chemicals, Pittsburgh, Pa.),agitated with an air mixer for 1 minute and degassed under vacuum (500mm Hg) for 3 minutes. The solution was knife coated between two 15.2 cmwide silicone-coated PET release liners (102 μm thick, CourtauldsAerospace, Inc., Glendale, Calif.) at a thickness of 76 μm, cured with atemperature ramp from 50° C. to 120° C. (3.5° C./min) and postcured at90° C. for 16-17 hours.

EXAMPLE 3B

Example 3B was prepared as described in Example 3A except 0.013 g ofYGOH fluorescent dye, (structure VI) was used in place of the SY98fluorescent dye.

EXAMPLE 3C

In this example a semi-IPN was prepared with an ethylene-methacrylicacid copolymer (EMAA), Nucrel 699 (DuPont Chemicals, Wilmington, Del.)and monofunctional and diftinctional acrylate monomers. The fluorescentdye was an acrylate functional fluorescent dye (YGOAc, see structure VIIabove).

To 19.0 g ofa Nucrel 699 polymer melt prepared in a 125° C. Brabendermixing head at 50 rpm, 0.12 g Tinuvin 770; 0.12 g Chimassorb 944; 0.24 gDarocur 4265; 0.24 g EBAD; and 0.045 g YGOAc dissolved in 4.51 g POEAwere added. After the final addition, mixing continued for five minutesat 125° C. (120 rpm). The mixture was removed and pressed between 102 μmPET-silicone release liners into 102 μm films using a platen press at208 MPa (30,000 psi) heated to 110° C., then cured for 15 minutes oneach side simultaneously using Sylvania 350BL bulbs.

EXAMPLE 3D

In this example a semi-IPN was prepared with an aliphatic polyesterpolyurethane, PU, Morthane L424.167 and monofunctional and difunctionalacrylate monomers. Weathering additives were added to help protect boththe dye and polymer. The fluorescent dye was an acrylate functionalfluorescent dye (YGOAc, see structure VII above).

To 19.0 g of a Morthane L424.167 polymer melt prepared in a 155° C.Brabender mixing head (50 rpm) were added 0.12 g Tinuvin 622; 0.12 gTinuvin 770; 0.045 g YGOAc; 0.24 g Darocur 4265; 0.24 g EBAD; and 4.51 gPOEA. After the final addition, mixing continued for five minutes at155° C. and 100 rpm. The mixture was removed and pressed between 4 milPET-silicone release liners into 102 μm films using a platen press at172 MPa (25,000 psi) heated to 120° C. and then cured for 15 minutes oneach side simultaneously using Sylvania 350BL bulbs.

TABLE 3 Migration and Extraction Studies % Dye % Dye Retention RetentionExample IPN/ after after Number semi-IPN Dye Migration Extraction 3A IPNSY98 20  1 1E IPN YGOAc 97 84 3B IPN YGOH 97 98 3C semi-IPN YGOAc 96 na3D semi-IPN YGOAc 99 na na = Not available

The data in Table 3 show that the functional dyes, YGOH or YGOAc, werebound to the IPN networks and were not readily able to migrate or beeasily extracted. (Migration relates to physical removal of the dye.) Incontrast, the nonfunctional fluorescent dyc, SY98, almost completelymigrated out of the IPN materials and was completely extracted,indicating that the unbound dye was highly mobile in the IPN materials.The results from Table 3 strongly indicated that the functionalfluorescent dyes were covalently attached to the interpenetratingpolymer network.

EXAMPLE 4 Mechanical Properties

Several of the Examples previously described were subjected to tensiletesting and dynamic mechanical analysis as described earlier to examinethe range of properties that can be obtained from the IPN materials. Theresults from these tests are shown in Table 4.

TABLE 4 Mechanical Properties of Selected Examples Containing AcrylateSecond Phase % Ultimate Example Weathering (% Elongation Tensile ModulusTg Number Dye Retention) at Break (MPa) (MPa) (° C.) 1E 70 (232 hours) 14 28.4 955.0 9, 51 1F 74 (232 hours) 100 3.0 11.0 −12   1G 41 (232hours) 108 32.3 451.0 37 2B-1 77 (100 hours) 406 30.0 22.6 14

As shown in Table 4, the mechanical properties of these materials werevaried widely by changing the continuous first phase while keeping thedispersed acrylate second phase unchallenged. An optimal dyemicroenvironment was maintained through tle acrylac phaise whileobtaining a variety of physical properties through choice of thecontinuous first phase. This concept is clearly shown by comparing theresults in Table 4 for Example 1E and Example 1F where the % dyeretention for the two samples were almost identical whereas themechanical properties changed dramatically. Finally, it should be notedthat the mechanical properties described in Table 4 should not beconsidered as upper and lower limits. In general, the range ofmechanical properties that can be obtained will be more similar to therange of properties obtained when considering all possible first phasematerials as specified above.

EXAMPLE 5 Effect of HALS

The addition of hindered amine light stabilizers (HALS) was evaluated asto their effect on fluorescent dye durability. IPN films containingTinuvin 123™ (HALS) were prepared with loadings ranging from zero to twopercent HALS and weathered in accelerated weathering chambers asdescribed above. The sample preparation is given below while the data isshown in Table 5.

EXAMPLE 5A

In a 100 mL plastic beaker, 23.71 g of polyol KM-10-1733™ containingdissolved YGOH dye (0.125 g), (structure VI) was combined with asolution of 1.75 g IOA containing 0.125 g dissolved Perkadox™ 16 and0.05 g BYK-066™, a solution of 1.0 g EBAD containing 0.0075 g DBTDL, 2.0g IOA, 10.25 g EBAD, 1.00 g caprolactone acrylate, 0.38 g Uvinul N-3039™and 0.00 g Tinuvin 123™. The solution was mixed with a spatula, treatedwith 1 1.29 g of Desmodlir N-3300™, agitated with an air mixer for 1minute and degassed under vacuum (500 mm Hg) for 3 minutes. The solutionwas knife coated between two 15.2 cm wide silicone-coated PET releaseliners at a thickness of 102 μm, cured with a temperature ramp from 70°C. to 120° C. (2.5° C./min) and postcured at 90° C. for 16-17 hours.

EXAMPLE 5B

Example 5B was prepared according to Example 5A except that 0.05 gTinuvin 123™ and a total of 0.15 g of Perkadox 16™ were added.

EXAMPLE 5C

Example 5C was prepared according to Example 5A except that 0.25 gTinuvin 123™ and a total of 0.23 g of Perkadox 16™ were added.

EXAMPLE 5D

Example 5D was prepared according to Example 5A except that 0.50 gTinuvin 123™ and a total of 0.33 g of Perkadox 16™ were added.

EXAMPLE 5E

Example 5E was prepared according to Example 5A except that 1.0 gTinuvin 123™ and a total of 0.63 g of Perkadox 16™ were added.

TABLE 5 Effect of HALS Loading on Fluorescent Dye Durability % DyeRetained % HALS after 204 Hours Example Number (Tinuvin 123) Weathering5A 0.0 35 5B 0.1 55 5C 0.5 63 5D 1.0 61 5E 2.0 75

In Table 5, the data show that the fluorescent dye durability improvedwith increasing levels of HALS, at least tip to loadings of two percent.

EXAMPLE 6 Effect of Adding a Second Phase when Using NonfunctionalFluorescent Dyes

In this example, a nonfunctional fluorescent dye is added to a semi-IPNcomposition. Specifically, SY98 is added to an EMAA/Acrylate basedsemi-IPN. The samples were weathered according to ASTM G-26-96 in thexenon arc device and then analyzed for percent peak retention asdescribed above in the Weathering Studies section. The samplepreparation is described below while the weathering results are shown inTable 6.

EXAMPLE 6A

In this example a semi-IPN was prepared with an ethylene-methacrylicacid copolymer (EMAA), Nucrel 699 and monofunctional and difunctionalacrylate monomers. The fluorescent dye was a non-functional fluorescentdye (SY98, see structure V).

To 19.0 g of a Nucrel 699 polymer melt prepared in a 125° C. Brabendermixing head at 50 rpm, 0.12 g Tinuvin 770; 0.12 g Chimassorb 944; 0.24 gDarocur 4265; 0.24 g EBAD; and 0.045 g SY98 dissolved in 4.51 g POEAwere added. After the final addition, mixing continued for five minutesat 125° C. (120 rpm). The mixture was removed and pressed between 102 μmpolyethylene terephthalate (PET)-silicone release liners into filmsusing a platen press at 208 MPa (30,000 psi) heated to 110° C., thencured for 15 minutes on each side simultaneously using Sylvania 350BLbulbs.

EXAMPLE 6B

In this example an EMAA film was prepared with an ethylene-methacrylicacid copolymer, EMAA, (Nucrel 699) and a non-functional fluorescent dye(SY98, see structure V).

To 24.0 g of a Nucrel 699 polymer melt prepared in a 150° C. Brabendermixing head at 50 rpm, 0.24 g Chimassorb 944 and 0.045 g of SY98 wereadded. After the final addition, mixing continued for five minutes at150° C. (100 rpm). The mixture was removed and pressed between 102 μmpolyethylene terephthalate (PET)-silicone release liners into filmsusing a platen press at 172 MPa (25,000 psi) heated to 120° C.

TABLE 6 Effect of Using a Nonfunctional Fluorescent Dye on AcceleratedWeathering Film First Second Wt % Thickness 100 Ex. # Phase Phase DyeDye (mm) hours 6A  EMAA Acrylate SY98 0.2 0.13 25 6B* EMAA None SY98 0.20.10 11 *Comparative

The data in Table 6 show that when a nonfunctional fluorescent dye wasused, fluorescent dye retention was enhanced upon the addition of thesecond phase to the thermoplastic. This indicated that adding a secondcomponent to enhance fluorescent dye durability was useful even whenfunctional fluorescent dyes were not available or could not be used forother reasons.

EXAMPLE 7 Demonstration of Varying Levels of Dispersed Phase

In this example semi-IPNs were prepared with ethylene-methacrylic acidcopolymer, Nucrel 699, with varying levels of acrylate monomer. Acrylatelevels ranged from 0 to 40 weight percent. Examples were preparedaccording to example 2A-1 differing only in the amount of acrylatemonomer.

TABLE 7 Effect of Varying Levels of Acrylate on Percent Fluorescent DyeRetained % Fluorescent Dye Retained After 100 Example Number % TotalAcrylate hrs Weathering 2A-2*  0.0  9 7A  5.0 26 7B 10.0 34 7C 15.0 432A-1  20.0 54 7D 25.0 48 7E 30.0 56 7F 40.0 60 *Comparative

In Table 7, the data show the fluorescent dye retention improved withincreasing levels of acrylate with a significant improvement influorescent dye retention being observed at a level of 5% acrylate.

EXAMPLE 8 Demonstration of Enhanced Retention of Fluorescent EmissionIntensities

The fluorescent emission intensities of examples 2A-1, 2A-2, and 7A-Fwere measured before and alter weathering. Intensities were measured anda “% Fluorescent Emission Intensity Retained” value was calculated asdescribed in the Fluorescence section above.

TABLE 8 Percent Fluorescent Emission Retained % Fluorescent EmissionIntensity Retained after 100 Example # % Total Acrylate hours Weathering2A-2*  0.0 37 7A  5.0 82 7B 10.0 98 7C 15.0 96 2A-1  20.0 102  7D 25.089 7E 30.0 95 7F 40.0 88 *Comparative

In Table 8 the data show that the retention of fluorescent emissionintensity increased with increasing levels of acrylate then reached aplateau at 10% acrylate.

EXAMPLE 9 Demonstration of Other Applicable Dye Classcs BesidesThioxanthene

The benefit of a dispersed second phase can be shown in numerous classesof dyes including thioxantheiet and perylene imide. Semi-IPN, Example9A, was prepared with a perylene imide fluorescent dye, Lumogen™ F Red300 (BASF, Rensselaer, N.Y.) according to the method of Example 2A-1,differing only in the replacement of the 0.14% YGOAc thioxanthenefluorescent dye with 0.2% Lumogen F Red 300 perylene imide fluorescentdye. Example 9B was the comparative made according to Example 9A butwithout acrylate monomers or a photoinitiator.

TABLE 9 Percent Perylene Imide Fluorescent Dye Lumogen F Red 300Retention after Weathering 100 200 300 Example No. Description hourshours hours 9A  EMAA with 79 65 52 Acrylate 9B* EMAA without 76 40 14Acrylate *Comparative

In Table 9, the data show that L umogen F Red 300, a perylene imidefluorescent dye, also benefited from the addition of a dispersed secondphase.

Various modifications and alterations of this invention will becomeapparent to those skilled in the art without departing from the scopeand intent of this invention, and it should be understood that thisinvention is not to be unduly limited to the illustrative embodimentsset forth herein.

What is claimed is:
 1. An interpenetrating polymer network (IPN) orsemi-interpenetrating polymer network (semi-IPN) comprising: a) a firstphase being continuous and comprising a flexible polymer, and b) asecond phase being a fluorescently durable dispersed or continuous phaseand comprising a fluorescent dye and a polymer, wherein said polymerenhances durability of the fluorescent dye; which is a free-standingfluorescent film.
 2. An article comprising an interpenetrating polymernetwork (IPN) or semi-interpenetrating polymer network (semi-IPN)comprising: a) a first phase being continuous and comprising a flexiblepolymer, and b) a second phase being a fluorescently durable dispersedor continuous phase and comprising a fluorescent dye and a polymer,wherein said polymer enhances durability of the fluorescent dye.
 3. Thearticle according to claim 2 which is a fluorescent traffic sign orsafety device.
 4. The article according to claim 2 which is a pavementmarking paint or tape.
 5. The article according to claim 2 which is areflective film.
 6. The article according to claim 2 comprising afluorescent fiber or fabric.
 7. A multilayer construction compri siglayer of an interpenetrating polymer network (IPN) orsemi-interpenetrating polymer network (semi-IPN) comprising: a) a firstphase being continuous and comprising a flexible polymer, and b) asecond phase being a fluorescently durable dispersed or continuous phaseand comprising a fluorescent dye and a polymer, wherein said polymerenhances durability of the fluorescent dye.
 8. The multilaycrconstruction according to claim 7 further comprising a substrate,wherein said IPN or semi-IPN layer is substantially transparent, saidmultilayer construction being a pavement marking tape.